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Volumn 27, Issue 24, 2008, Pages 6427-6433

Synthesis, crystal structure, EPR and DFT studies, and redox properties of [2]tetramethyldisilacobaltocenophane

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; PARAFFINS; PARAMAGNETIC RESONANCE; POSITIVE IONS; PROBABILITY DENSITY FUNCTION; QUANTUM THEORY; SILICON; SYNTHESIS (CHEMICAL); TENSORS; X RAY DIFFRACTION ANALYSIS;

EID: 61849087986     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8003724     Document Type: Article
Times cited : (31)

References (86)
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    • We are not discussing rate constants and and thermodynamic parameters in detail because uncompensated solution resistance Ru and other factors of our experimental setup have a strong influence
    • u and other factors of our experimental setup have a strong influence.
  • 53
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    • The crystal data of 1 and 8 were collected on a Bruker X8Apex diffractometer with a CCD area detector and multi-layer mirror monochro-mated Mo Kα radiation. The structures were solved using direct methods, refined with the Shelx software package (Sheldrick, G. Acta Crystallogr. A64, 112, and expanded using Fourier techniques. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms were assigned to idealized positions and were included in structure factor calculations. Crystal data for 1: C14H20CoSi2, Mr, 303.41, brown block, 0.21 × 0.18 × 0.12 mm3, monoclinic space group P2√m, a, 8.2595(3) Å, b, 10.3127(5) Å, c, 8.5719(4) Å, β, 90.380(2)°, V, 730.12(6) Å3, Z, 2, pcalcd, 1.380 g cm-3, μ, 1.316 mm-1, F(000, 318, T, 99(2) K, R1, 0.0180, wR2, 0.0519, 3843 independent reflections
    • -1, F(000) = 1824, T = 100(2) K, Rl = 0.0314, wR2 = 0.0774, 3553 independent reflections (2θ ≤ 52.1°) and 230 parameters. Crystallographic data have been deposited with the Cambridge Crystallographic Data Center as Supplementary Publication Nos. CCDC-685949 and 685950. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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    • 61849159326 scopus 로고    scopus 로고
    • Heinze, J. Angew. Chem. 1984, 96, 823 Angew. Chem., Int. Ed. 1984, 23, 831.
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  • 71
    • 0003998388 scopus 로고    scopus 로고
    • Lide, D. R, Ed, 77th ed, CRC Press: Boca Raton, FL
    • (b) Lide, D. R., Ed. CRC Handbook of Chemistry and Physics, 77th ed.; CRC Press: Boca Raton, FL, 1997.
    • (1997) CRC Handbook of Chemistry and Physics
  • 74
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    • Ph.D. Thesis, University of Alberta, Edmonton, Alberta, Canada
    • (a) Huzinaga, S. Ph.D. Thesis, University of Alberta, Edmonton, Alberta, Canada, 1971.
    • (1971)
    • Huzinaga, S.1
  • 79
    • 61849183634 scopus 로고    scopus 로고
    • Malkin, V. G, Malkina, O. L, Reviakine, R, Arbouznikov, A. V, Kaupp, M, Schimmelpfennig, B, Malkin, I, Helgaker, T, Ruud, K. MAG-Respect, Version 1.2, 2003
    • Malkin, V. G.; Malkina, O. L.; Reviakine, R.; Arbouznikov, A. V.; Kaupp, M.; Schimmelpfennig, B.; Malkin, I.; Helgaker, T.; Ruud, K. MAG-Respect, Version 1.2, 2003.
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    • Schimmelpfennig, B. Ph.D. Thesis, Stockholms Universitet, 1996.
    • (b) Schimmelpfennig, B. Ph.D. Thesis, Stockholms Universitet, 1996.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.