Direct determination of dopant site selectivity in ordered perovskite CaCu3Ti4O12 polycrystals by aberration-corrected STEM

Advanced Materials

Volumn 21, Issue 8, 2009, Pages 885-889

  Choi, Si Young ^c,d   Chung, Sung Yoon ^a,b   Yamamoto, Takahisa ^c,e   Ikuhara, Yuichi ^c,e  

^a Inha University   (South Korea)

^b Nalphates LLC   (United States)

^c UNIVERSITY OF TOKYO   (Japan)

^d Korea Institute of Material Science   (South Korea)

^e JAPAN FINE CERAMICS CENTER   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABERRATIONS; ATOMIC SPECTROSCOPY; CALCIUM; DOPING (ADDITIVES); ENERGY DISSIPATION; LANTHANUM; OXIDE MINERALS; PEROVSKITE; POLYCRYSTALS; POSITIVE IONS; SCANNING ELECTRON MICROSCOPY; STRONTIUM COMPOUNDS; TRANSMISSION ELECTRON MICROSCOPY;

ABERRATION-CORRECTED STEMS; ALIOVALENT; ATOMIC COLUMNS; CHEMICAL IDENTIFICATIONS; COMPLEX PEROVSKITES; DIRECT DETERMINATIONS; DIRECT VISUALIZATIONS; DOPANT SITE SELECTIVITIES; ELECTRON ENERGY-LOSS SPECTROSCOPIES; IMAGE SIMULATIONS; ORDERED BEHAVIORS; ORDERED PEROVSKITES; SCANNING TRANSMISSION ELECTRON MICROSCOPIES; SPHERICAL ABERRATION CORRECTORS;

ELECTRON ENERGY LOSS SPECTROSCOPY;

EID: 60849096105     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/adma.200802728     Document Type: Article

References (43)

1. L. Pauling, J. Am. Chem. Soc. 1929, 51, 1010.
2. M. A. Subramanian, D. Li, N. Duan, B. A. Reisner, A. W. Sleight, J. Solid State Chem. 2000, 151, 323.
3. A. P. Ramirez, M. A. Subramanian, M. Gardel, G. Blumberg, D. Li, T. Vogt, S. M. Shapiro, Solid State Commun. 2000, 115, 217.
4. C. C. Homes, T. Vogt, S. M. Shapiro, S. Wakimoto, A. P. Ramirez, Science 2001, 293, 673.
5. L. He, J. B. Neaton, M. H. Cohen, D. Vanderbilt, C. C. Homes, Phys. Rev. B 2002, 65, 214112.
6. L. He, J. B. Neaton, D. Vanderbilt, M. H. Cohen, Phys. Rev. B 2003, 67, 012103.
7. a) D. C. Sinclair, T. B. Adams, F. D. Morrison, A. R. West, Appl. Phys. Lett. 2002, 80, 2153.
8. b) T. B. Adams, D. C. Sinclair, A. R. West, Adv. Mater. 2002, 14, 1321.
9. c) T. B. Adams, D. C. Sinclair, A. R. West, Phys. Rev. B 2006, 73, 094124.
10. S.-Y. Chung, I.-D. Kim, S.-J. L. Kang, Nat. Mater. 2004, 3, 774.
11. M. H. Cohen, J. B. Neaton, L. He, D. Vanderbilt, J. Appl. Phys. 2003, 94, 3299.
12. S. Krohns, P. Lunkenheimer, S. G. Ebbinghaus, A. Loidl, Appl. Phys. Lett. 2007, 91, 022910.
13. L. Wu, Y. Zhu, S. Park, S. Shapiro, G. Shirane, J. Tafto, Phys. Rev. B 2005, 77, 014118.
14. a) T.-T. Fang, C. P. Liu, Chem. Mater. 2005, 17, 5167.
15. b) M.-H. Whangbo, M. A. Subramanian, Chem. Mater. 2006, 18, 3257.
16. a) S.-Y. Chung, Appl. Phys. Lett. 2005, 87, 052901.
17. b) S.-Y. Chung, S.-Y. Choi, T. Yamamoto, Y. Ikuhara, Appl. Phys. Lett. 2006, 89, 121903.
18. a) W. Li, R. W. Schwartz, Appl. Phys. Lett. 2006, 89, 242906.
19. b) W. Li, R. W. Schwartz, A. Chen, J. Zhu, Appl. Phys. Lett. 2007, 90, 112901.
20. a) S.-Y. Chung, S.-I. Lee, J.-H. Choi, S.-Y. Choi, Appl. Phys. Lett. 2006, 89, 191907.
21. b) S.-Y. Chung, J.-H. Choi, J.-K. Choi, Appl. Phys. Lett. 2007, 97, 091912.
22. a) S.-Y. Chung, S.-Y. Choi, T. Yamamoto, Y. Ikuhara, S.-J. L. Kang, Appl. Phys. Lett. 2006, 88, 091917.
23. b) R. K. Grubbs, E. L. Venturini, P. G. Clem, J. J. Richardson, B. A. Tuttle, G. A. Samara, Phys. Rev. B 2005, 72, 104111.
24. a) M. Haider, S. Uhlemann, E. Schwan, B. Kabius, H. Rose, K. Urban, Nature 1998, 392, 768.
25. b) C. L. Jia, M. Lentzen, K. Urban, Science 2003, 299, 870.
26. c) C. L. Jia, S.-B. Mi, K. Urban, I. Vrejoiu, M. Alexe, D. Hesse, Nat. Mater. 2008, 7, 57.
27. a) L. C. Gontard, L.-Y. Chang, C. J. D. Hetherington, A. I. Kirkland, D. Ozkaya, R. E. Dunin-Borkowski, Angew. Chem. Int. Ed. 2007, 46, 3683.
28. b) C. J. D. Hetherington, L-Y. S. Chang, S. Haigh, P. D. Nellist, L. C. Gontard, R. E. Dunin-Borkowski, A. I. Kirkland, Microsc. Microanal. 2008, 74, 60.
29. P. E. Batson, N. Dellby, O. L. Krivanek, Nature 2002, 478, 617.
30. P. D. Nellist, M. F. Chisholm, N. Dellby, O. L. Krivanek, M. F. Murfitt, Z. S. Szilagyi, A. R. Lupini, A. Borisevich. W. H. Sides, Jr, S. J. Pennycook, Science 2004, 305, 1741.
31. S.-Y. Chung, S.-Y. Choi, T. Yamamoto, Y. Ikuhara, Phys. Rev. Lett. 2008, 100, 125502.
32. W. D. Pyrz, D. A. Blom, T. Vogt, D. J. Buttrey, Angew. Chem. Int. Ed. 2008, 47, 2788.
33. a) M. Bosman, V. J. Keast, J. L. García-Muñoz, A. J. D'Alfonso, S. D. Findlay, L. J. Allen, Phys. Rev. Lett. 2007, 99, 086102.
34. b) K. Kimoto, T. Asaka, T. Nagai, M. Saito, Y. Matsui, K. Ishizuka, Nature 2007, 450, 702.
35. c) D. A. Muller, L. Fitting Kourkoutis, M. Murfitt, J. H. Song, H. Y. Hwang, J. Silcox, N. Dellby, O. L. Krivanek, Science 2008, 319, 1073.
36. B. Bochu, M. N. Deschizeaux, J. C. Joubert, A. Collomb, J. Chenavas, M. Marezio, J. Solid State Chem. 1979, 29, 291.
37. a) A. Ohtomo, D. A. Muller, J. L. Grazul, H. Y. Hwang, Nature 2002, 419, 378-380.
38. b) J. M. LeBeau, S. D. Findlay, L. J. Allen, S. Stemmer, Phys. Rev. Lett. 2008, 100, 206101.
39. R. F. Egerton, Electron Energy Loss Spectroscopy in the Electron Microscope, Plenum Press, New York 1996.
40. a) J. E. Huhyee, E. A. Keiter, R. L. Keiter, Inorganic Chemistry, Principles of Structure and Reactivity, 4th ed. HarperCollins College Publishers, New York 1993, pp. 387-471.
41. b) H. L. Schläfer, G. Gliemann, Basic Principles of Ligand Field Theory, Wiley-Interscience. New York 1969, pp. 1-117.
42. A. Prodi, E. Gilioli, A. Gauzzi, F. Licci, M. Marezio, F. Bolzoni, Q. Huang, A. Santoro, J. W. Lynn, Nat. Mater. 2004, 3, 48.
43. M. Avdeev, V. B. Nalbandyan, lnorg. Chem. 2006, 45, 2217.