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58249100992
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For experimental procedures and more studies, see the Supporting Information;
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a) For experimental procedures and more studies, see the Supporting Information;
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53
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58249113808
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4NCl).
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4NCl).
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58249117610
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The occurrence of reductive by-products could not be eliminated by careful drying of the reagents and solvents and transfer of the reaction to a glovebox
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a) The occurrence of reductive by-products could not be eliminated by careful drying of the reagents and solvents and transfer of the reaction to a glovebox.
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56
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0031871453
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1-2], we postulate competitive hydrodehalogenation: b) G. Cahiez, H. Avedissian, Synthesis 1998, 1199-1205;
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3 by Grignard reagents see Refs. [6a] and [14].
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62
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Single electron transfer into the π* orbital of the aryl bromide is reversible, and the π*-σ* transition required for dissociation of the C-Br bond is slow
-
b) Single electron transfer into the π* orbital of the aryl bromide is reversible, and the π*-σ* transition required for dissociation of the C-Br bond is slow.
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63
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58249102063
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Alkyl halides in cross-coupling reactions:A. C. Frisch, M. Beller, Angew. Chem. 2005, 117, 680-695;
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3 with alkyl-MgX. The THF-soluble dark brown complex was not isolated. See Refs. [6] and [14].
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3 with alkyl-MgX. The THF-soluble dark brown complex was not isolated. See Refs. [6] and [14].
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66
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0001044296
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For an electrochemical direct coupling, see
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