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Volumn 45, Issue 36, 2006, Pages 6053-6056

Regioselective iron-catalyzed allylic amination

Author keywords

Allylic amination; Arylamines; Homogeneous catalysis; Iron; Regioselectivity

Indexed keywords

AMINES; CARBONATES; CATALYSIS; IRON; STEREOCHEMISTRY;

EID: 33748795799     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200602261     Document Type: Article
Times cited : (132)

References (24)
  • 3
    • 0042379988 scopus 로고    scopus 로고
    • a) Review on asymmetric allylic substitutions: B. M. Trost, M. L. Crawley, Chem. Rev. 2003, 103, 2921;
    • (2003) Chem. Rev. , vol.103 , pp. 2921
    • Trost, B.M.1    Crawley, M.L.2
  • 19
    • 33748803771 scopus 로고    scopus 로고
    • note
    • "Direct nucleophiles" are distinguished by the fact that the nucleophilic center does not have to be activated prior to the reaction (through, for example, deprotonation).
  • 20
    • 0030968870 scopus 로고    scopus 로고
    • and references therein
    • Oxidative, iron-catalyzed aminations of unactivated olefins: R. S. Srivastava, K. M. Nicholas, J. Am. Chem. Soc. 1997, 119, 3302, and references therein.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 3302
    • Srivastava, R.S.1    Nicholas, K.M.2
  • 21
    • 0037978732 scopus 로고
    • For a common reaction between iron carbonyl complexes and nitrogen bases, see: a) W. Hieber, N. Kahlen, Chem. Ber. 1958, 91, 2223;
    • (1958) Chem. Ber. , vol.91 , pp. 2223
    • Hieber, W.1    Kahlen, N.2
  • 23
    • 0032416884 scopus 로고    scopus 로고
    • [8] The electronic influence of various substituents on conversion and yield in the stoichiometric amination of π-allyl iron complexes has been described: S. Nakanishi, K. Okamoto, H. Yamaguchi, T. Takata, Synthesis 1998, 1735.
    • (1998) Synthesis , pp. 1735
    • Nakanishi, S.1    Okamoto, K.2    Yamaguchi, H.3    Takata, T.4
  • 24
    • 2542504340 scopus 로고    scopus 로고
    • The only broadly applicable procedure for the allylic substitution of higher-substituted allyl carbonates by the mechanism involving a σ-allyl metal fragment to be reported so far was published by Martin et al.: B. L. Ashfeld, K. A. Miller, S. F. Martin, Org. Lett. 2004, 6, 1321.
    • (2004) Org. Lett. , vol.6 , pp. 1321
    • Ashfeld, B.L.1    Miller, K.A.2    Martin, S.F.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.