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Volumn 10, Issue 14, 2008, Pages 3069-3072

Synthesis and crystal structures of isolable terminal aryl hexatriyne and octatetrayne derivatives: Ar-(C≡C)nH (n = 3, 4)

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EID: 58149461106     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol801121p     Document Type: Article
Times cited : (41)

References (43)
  • 30
    • 12344269243 scopus 로고    scopus 로고
    • Alternative syntheses of diarylpolyynes. (a) Luu, T.; Elliott, E.; Slepkov, A. D.; Eisler, S.; McDonald, R.; Hegmann, F. A.; Tykwinski, R. R. Org. Lett. 2005, 7, 51.
    • Alternative syntheses of diarylpolyynes. (a) Luu, T.; Elliott, E.; Slepkov, A. D.; Eisler, S.; McDonald, R.; Hegmann, F. A.; Tykwinski, R. R. Org. Lett. 2005, 7, 51.
  • 38
    • 59949090147 scopus 로고    scopus 로고
    • X-ray experiments: SMART 6K CCD area detector diffractometer, graphite-monochromated Mo Kα radiation (γ, 0.71073 Å, SHELXTL 6.14 software (Bruker AXS, Madison WI, USA, 2003, At room temperature, single crystals deteriorated rapidly, both in and out of mother liquor. The diffraction of 4 and 7 was weak, mean I/σ(I, 5.0 and 4.3, respectively. Crystal data for C30H29N (4, C34H29N (7, and C32H 29N (10, M, 403.54/451.58/427.56, T, 120 K, monoclinic, space group P21/c (no. 14, a, 19.295(2)/21.065(3)/5.824(1, b, 5.7668(9)/5.6665(8)/19.988(2, c, 22.291(3)/22.090(4)/21.420(2) Å, β, 107.45(1)/98.48(5)/96. 61(1)°, V, 2366.2(5)/2607.9(7)/2476.9(5) Å3, Z, 4, Dc, 1.133/1.150/1.147 g/cm, 13441/13239/24480 reflections measu
    • 2) = 11.8/10.5/12.8% (all data). CCDC 679671 (4), 679672 (7), 679673 (10) contain the supplementary crystallographic data for this paper, which can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
  • 40
    • 84890987272 scopus 로고    scopus 로고
    • Haley, M. M, Tykwinski, R. R, Eds, Wiley-VCH: Weinheim, Germany
    • (a) Carbon-Rich Compounds: From Molecules to Materials; Haley, M. M., Tykwinski, R. R., Eds.; Wiley-VCH: Weinheim, Germany, 2006.
    • (2006) Carbon-Rich Compounds: From Molecules to Materials
  • 41
    • 84891029339 scopus 로고    scopus 로고
    • Diederich, F, Stang, P. J, Tykwinski, R. R, Eds, Wiley-VCH: Weinheim, Germany
    • (b) Acetylene Chemistry: Chemistry, Biology and Material Science; Diederich, F., Stang, P. J., Tykwinski, R. R., Eds.; Wiley-VCH: Weinheim, Germany, 2005.
    • (2005) Acetylene Chemistry: Chemistry, Biology and Material Science


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