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33646570011
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For mechanistic aspects of such alkyne dimerization, see ref 4.
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24
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33646547668
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note
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In fact, the PL spectrum of (E)-CPEY doped in NPB (ca. 1:1 w/w) in a vacuum-deposited film showed a sharp emission around 455 nm without tailing to long wavelength (Figure 1). This strongly suggests that (E)-CPEY excimer formation was hindered even by NPB in the doped film and thus excludes again the possibility of exciplex formation between (E)-CPEY and NPB.
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