Synthesis of heterometallic Group 13 nanoclusters and inks for oxide thin-film transistors

Angewandte Chemie - International Edition

Volumn 47, Issue 49, 2008, Pages 9484-9486

  Mensinger, Zachary L ^b   Gatlin, Jason T ^b   Meyers, Stephen T ^a   Zakharov, Lev N ^b   Keszler, Douglas A ^a   Johnson, Darren W ^b  

^a OREGON STATE UNIVERSITY   (United States)

^b UNIVERSITY OF OREGON   (United States)

Author keywords

Cluster compounds; Gallium; Heterometallic complexes; Nanomaterials; Thin films

Indexed keywords

CHEMICAL REACTIONS; GALLIUM ALLOYS; HYDRATES; NANOCLUSTERS; NANOSTRUCTURED MATERIALS; NANOSTRUCTURES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; SEMICONDUCTING ORGANIC COMPOUNDS; THICK FILMS; THIN FILM DEVICES; THIN FILM TRANSISTORS; TRANSISTORS;

CHEMICAL EQUATIONS; CLUSTER COMPOUNDS; HETEROMETALLIC; HETEROMETALLIC COMPLEXES; NANOMATERIALS; NITROSO; SYNTHESIS OF;

COMPLEXATION;

EID: 56749168069     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803514     Document Type: Article

References (28)

1. E. Rather, J. T. Gatlin, P. G. Nixon, T. Tsukamoto, V. Kravtsov, D. W. Johnson, J. Am. Chem. Soc. 2005, 127, 3242.
2. J. T. Gatlin, Z. L. Mensinger, L. N. Zakharov, D. MacInnes, D. W. Johnson, Inorg. Chem. 2008, 47, 1267.
3. W. H. Casey, Chem. Rev. 2006, 106, 1.
4. W. H. Casey, M. M. Olmstead, B. L. Phillips, Inorg. Chem. 2005, 44, 4888.
5. J. C. Goodwin, S. J. Teat, S. L. Heath, Angew. Chem. 2004, 116, 4129;
6. Angew. Chem. Int. Ed. 2004, 43, 4037.
7. W. Seichter, H.-J. Mogel, P. Brand, D. Salah, Eur. J. Inorg. Chem. 1998, 795.
8. W. Schmitt, E. Baissa, A. Mandel, C. E. Anson, A. K. Powell, Angew. Chem. 2001, 113, 3689;
9. Angew. Chem. Int. Ed. 2001, 40, 3577.
10. O. A. Gerasko, E. A. Mainicheva, D. Y. Naumov, N. V. Kuratieva, M. N. Sokolov, V. P. Fedin, Inorg. Chem. 2005, 44, 4133.
11. S. M. Bradley, R. A. Kydd, R. Yamdagni, J. Chem. Soc. Dalton Trans. 1990, 413.
12. J. Kudynska, H. A. Buckmaster, K. Kawano, S. M. Bradley, R. A. Kydd, J. Chem. Phys. 1993, 99, 3329.
13. A. Oszkó, J. Kiss, I. Kiricsi, Phys. Chem. Chem. Phys. 1999, 1, 2565.
14. W. O. Parker, Jr., R. Millini, I. Kiricsi, Inorg. Chem. 1997, 36, 571.
15. A. P. Lee, B. L. Phillips, M. M. Olmstead, W. H. Casey, Inorg. Chem. 2001, 40, 4485.
16. K. L. Fujdala, T. D. Tilley, J. Am. Chem. Soc. 2001, 123, 10133.
17. R. Murugavel, M. G. Walawalkar, M. Dan, H. W. Roesky, C. N. R. Rao, Acc. Chem. Res. 2004, 37, 763.
18. P. Sekar, E. C. Greyson, J. E. Barton, T. W. Odom, J. Am. Chem. Soc. 2005, 127, 2054.
19. H. S. Kim, P. D. Byrne, A. Facchetti, T. J. Marks, J. Am. Chem. Soc. 2008, 130, 12580.
20. H. Q. Chiang, D. Hong, C. M. Hung, R. E. Presley, J. F. Wager, C.-H. Park, D. A. Keszler, G. S. Herman, J. Vac. Sci. Technol. 2006, 24, 2702.
21. J. F. Wager, D. A. Keszler, R. E. Presley, Transparent Electronics, 1st ed., Springer, Berlin, 2008.
22. Single-crystal X-ray diffraction data on multiple single crystals confirmed the Ga/In ratio to be 7:6. This ratio is also apparent in the bulk thin-film Ga/In ratio. Preliminary elemental analysis and electron-probe microanalysis (EPMA) data also suggest a similar ratio in the bulk solid isolated from the reaction mixture.
23. We have not been able to prepare gram quantities of these compounds without the addition of an appropriate nitroso reagent. Although the role of this compound in cluster formation is not completely understood, it is vital to the high-yielding, gram-scale synthesis. Efforts to prepare Fe13 and In13 clusters in using a similar method have so far failed.
24. R. E. Presley, D. Honga, H. Q. Chiang, C. M. Hunga, R. L. Hoffman, J. F. Wager, Solid-State Electron. 2006, 50, 500.
25. K. Nomura, H. Ohta, A. Takagi, T. Kamiya, M. Hirano, H. Hosono, Nature 2004, 432, 488.
26. S. T. Meyers, J. T. Anderson, D. Hong, C. M. Hung, J. F. Wager, D. A. Keszler, Chem. Mater. 2007, 19, 4023.
27. J. T. Anderson, C. L. Munsee, C. M. Hung, T. M. Phung, G. S. Herman, D. C. Johnson, J. F. Wager, D. A. Keszler, Adv. Funct. Mater. 2007, 17, 2117.
28. A. M. Ako, O. Waldmann, V. Mereacre, F. Klower, I. J. Hewitt, C. E. Anson, H. U. Gudel, A. K. Powell, Inorg. Chem. 2007, 46, 756.