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Axial ligand coordinations in solution for V(IV) derivatives of 5-mono, 5,10-di, and 5,10,15-tri-meso-nitro-substituted octaethyl porphyrins are observed by the bathochromic shifts of the UV-vis bands as shown. UV-vis in chloroform (λmax at 295 K, for VO[NO2)OEP, 411, 538, and 577 nm; for VO[(NO2)OEP](py, 426, 547, and 580 nm; for VO[(NO2)2OEP, 413, 540, and 579 nm; for VO[(NO 2)2-OEP](py, 428, 551, and 587 nm; for VO[(NO 2)3OEP, 417, 545, and 582 nm; and for VO[(NO 2)3OEP]py, 432, 557, and 589 nm
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3OEP](py), 432, 557, and 589 nm.
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