Twisting the porphyrin ring to enhance epoxidation enantioselectivity

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2002, Pages 2956-2960

  Gazeau, Stéphanie ^a   Pécaut, Jacques ^a   Haddad, Raid ^b,c   Shelnutt, John A ^b,c   Marchon, Jean Claude ^a  

^a CEA GRENOBLE   (France)

^b SANDIA NATIONAL LABORATORIES   (United States)

^c University of New Mexico   (United States)

Author keywords

Asymmetric catalysis; Enantioselectivity; Epoxidation; Manganese; Porphyrinoids

Indexed keywords

ENANTIOSELECTIVITY; MANGANESE COMPOUNDS;

ASYMMETRIC CATALYSIS; CATALYTIC EPOXIDATION; MANGANESE COMPLEXES; PORPHYRIN RINGS; PORPHYRINOIDS;

PORPHYRINS;

DIHYDRONAPHTHALENE; MANGANESE DERIVATIVE; NAPHTHALENE DERIVATIVE; PORPHYRIN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; ENANTIOMER; ENANTIOSELECTIVITY; EPOXIDATION; REACTION OPTIMIZATION; STRUCTURE ANALYSIS;

EID: 0036840057     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200211)2002:11<2956::aid-ejic2956>3.0.co;2-%23     Document Type: Article

References (11)

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11. Note added in proof (August 28, 2002): dynamics simulations clearly indicate that exchange processes occur between inward/equatorial and outward/axial conformations of the carbonyl groups. The length of the strap influences these interconversions: R. Haddad, S. Gazeau, J. Pécaut, J.-C. Marchon, C. J. Medforth, J. A. Shelnutt, J. Am. Chem. Soc., submitted.