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See, for instance: a) G. Schmid, in: Nanoparticles, from Theory to Application, VCH, Weinheim, 2004;
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36749088059
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b) I. Favier, M. Gómez, G. Muller, M. R. Axet, S. Castillón, C. Claver, S. Jansat, B. Chaudret, K. Philippot, Adv. Synth. Catal. 2007, 349, 2459.
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See for example: a
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See for example: a) M. Diéguez, O. Pàmies, C. Claver, Chem. Rev. 2004, 104, 3189;
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See for instance: a) N. T. S. Phan, M. van der Sluys, C. W. Jones, Adv. Synth. Catal. 2006, 348, 609;
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0037448329
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The use of reactivity patterns is hampered due to the difficulty to find a reaction that only works with heteregeneous catalysts or viceversa (see ref.[6h, For recent examples, see: a) J. A. Widegren, R. G. Finke, J. Mol. Catal. A: Chem. 2003, 191, 187;
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Mata, Y.1
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45
-
-
56649093925
-
-
Several complexes that may be involved have a molecular mass slightly above 700, but this does not seem to influence the results
-
Several complexes that may be involved have a molecular mass slightly above 700, but this does not seem to influence the results.
-
-
-
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46
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0033533561
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0033152039
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b) N. J. Hovestad, E. B. Eggeling, H. J. Heidbüchel, J. T. B. H. Jastrzebski, U. Kragl, W. Keim, D. Vogt, G. van Koten, Angew. Chem. Int. Ed. 1999, 38, 1655;
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0030564122
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a) V. V. Volkov, G. van Tendeloo, G. A. Tsirkov, N. V. Cherkashina, M. N. Vargaftik, I. I. Moiseev, V. M. Novotortsev, A. V. Kvit, A. L. Chuvilin, J. Cryst. Growth 1996, 163, 377;
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b) M. K. Starchevsky, S. L. Hladiy, Y. A. Pazdersky, M. N. Vargaftik, I. I. Moiseev, J. Mol. Cat. A: Chem. 1999, 146, 229;
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57
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0042836770
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Eds, K. I. Thomas, K. I. Zamaraev, Blackwell, Oxford
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18744372139
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59
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85022571014
-
-
Schmid and co-workers have found that usually the ideal icosahedron arrangement is distorted and forms a cubooctahedron geometry. See for instance: a G. Schmid, M. Harms, J.-O. Malm, J.-O. Bovin, J. van Ruitenbeck, H. W. Zandbergen, W. T. Fu, J. Am. Chem. Soc. 1993, 115, 2046;
-
Schmid and co-workers have found that usually the ideal icosahedron arrangement is distorted and forms a cubooctahedron geometry. See for instance: a) G. Schmid, M. Harms, J.-O. Malm, J.-O. Bovin, J. van Ruitenbeck, H. W. Zandbergen, W. T. Fu, J. Am. Chem. Soc. 1993, 115, 2046;
-
-
-
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60
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84990148254
-
-
b) G. Schmid, B. Morun, J.-O. Malm, Angew. Chem. Int. Ed. Engl. 1989, 28, 778;
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Schmid, G.1
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Malm, J.-O.3
-
61
-
-
56649084658
-
-
ref.[1a
-
[1a]
-
-
-
-
62
-
-
0347134347
-
-
a) M. N. Vargaftik, I. I. Moiseev, D. I. Kochubei, K. I. Zamaraev, Faraday Discuss. 1992, 92, 13;
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Faraday Discuss
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-
-
Vargaftik, M.N.1
Moiseev, I.I.2
Kochubei, D.I.3
Zamaraev, K.I.4
-
64
-
-
56649086216
-
-
This is meant as a rough calculation; also, the clusters are different in nature, as the Moiseev cluster is charged and the present ones contain Pd0
-
This is meant as a rough calculation; also, the clusters are different in nature, as the Moiseev cluster is charged and the present ones contain Pd(0).
-
-
-
-
65
-
-
0003441482
-
Palladium Reagents and Catalysis
-
For recent reviews on Pd-catalyzed allylic substitution, see: a, Wiley, New York
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For recent reviews on Pd-catalyzed allylic substitution, see: a) J. Tsuji, Palladium Reagents and Catalysis, in: Innovations in Organic Synthesis, Wiley, New York, 1995;
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(1995)
Innovations in Organic Synthesis
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Tsuji, J.1
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68
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0000687774
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Eds, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer-Verlag, Berlin, Chapter 24;
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d) A. Pfaltz, M. Lautens, in: Comprehensive Asymmetric Catalysis, (Eds.: E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer-Verlag, Berlin, 1999, Vol. 2, Chapter 24;
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Comprehensive Asymmetric Catalysis
, vol.2
-
-
Pfaltz, A.1
Lautens, M.2
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70
-
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4043123499
-
-
for recent reviews on Pd-catalyzed Heck reactions, see: f L. F. Tietze, H. Ila, H. P. Bell, Chem. Rev. 2004, 104, 3453;
-
for recent reviews on Pd-catalyzed Heck reactions, see: f) L. F. Tietze, H. Ila, H. P. Bell, Chem. Rev. 2004, 104, 3453;
-
-
-
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71
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0141431960
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g) L. X. Dai, T. Tu, S. L. You, W. P. Deng, X. L. Hou, Acc. Chem. Res. 2003, 36, 659;
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Dai, L.X.1
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72
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0035903503
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h) C. Bolm, J. P. Hildebrand, K. Muñiz, N. Hermanns, Angew. Chem. Int. Ed. 2001, 40, 3284;
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Bolm, C.1
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73
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0003445429
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Eds, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer, Heidelberg
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i) M. Shibasaki, E. M. Vogl, in: Comprehensive Asymmetric Catalysis, (Eds.: E. N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Heidelberg, 1999;
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Shibasaki, M.1
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75
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0003779363
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Eds, M. Beller, C. Bolm, Wiley-VCH, Weinheim
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k) M. Beller, T. H. Riermeier, G. Stark, in: Transition Metals for Organic Synthesis, (Eds.: M. Beller, C. Bolm), Wiley-VCH, Weinheim, 1998.
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(1998)
Transition Metals for Organic Synthesis
-
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Beller, M.1
Riermeier, T.H.2
Stark, G.3
-
77
-
-
56649098421
-
-
The recycling was done adding in every run 10 mol% of ligand
-
The recycling was done adding in every run 10 mol% of ligand.
-
-
-
-
78
-
-
56649120063
-
-
[4a] Therefore, the final catalytic suspension was cooled down to -70°C to favour the separation of the nanoparticles from the solution. Then, the resulting solution was removed. The remaining solid was washed with dichloromethane under argon and subsequently used as catalyst precursor.
-
[4a] Therefore, the final catalytic suspension was cooled down to -70°C to favour the separation of the nanoparticles from the solution. Then, the resulting solution was removed. The remaining solid was washed with dichloromethane under argon and subsequently used as catalyst precursor.
-
-
-
-
79
-
-
56649093922
-
-
For recovered Pd1 we found 42.59% of Pd and 2.11% of P. For recovered Pd5 we found 46.45% of Pd and 1.81% of P.
-
For recovered Pd1 we found 42.59% of Pd and 2.11% of P. For recovered Pd5 we found 46.45% of Pd and 1.81% of P.
-
-
-
-
80
-
-
56649112431
-
-
PhD Thesis, Universitat Rovira i Virgili
-
Y. Mata, PhD Thesis, Universitat Rovira i Virgili, 2007.
-
(2007)
-
-
Mata, Y.1
-
81
-
-
56649103259
-
-
+ is not observed.
-
+ is not observed.
-
-
-
-
82
-
-
0036719128
-
-
See, for instance: a
-
See, for instance: a) A. Howard, C. E. J. Mitchell, R. G. Egdell, Surf. Sci. 2002, 515, L504;
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(2002)
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Howard, A.1
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85
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14944367494
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C. C. Cassol, A. P. Umpierre, G. Machado, S. I. Wolke, J. Dupont, J. Am. Chem. Soc. 2005, 127, 3298.
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