Superelectrophilic intermediates in the synthesis of novel indenole derivatives via 1,5-cyclization reactions of 5-aryl-1-azapenta-1,4-dien-3-ones

Synthesis

Volumn , Issue 21, 2008, Pages 3397-3406

  Ghavtadze, Nugzar ^a   Fröhlich, Roland ^a   Bergander, Klaus ^a   Würthwein, Ernst Ulrich ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Carbocations; Cyclization; Indenoles; Penta 1,4 dien 3 ones; Quantum chemical calculations

Indexed keywords

ACIDS; ACTIVATION ENERGY; KETONES; ORGANIC COMPOUNDS; QUANTUM CHEMISTRY; THIOPHENE;

ACTIVATION BARRIERS; CARBOCATIONS; CYCLIZATION REACTIONS; GOOD YIELDS; HYDRAZONE; INDENOLES; NAZAROV REACTIONS; PENTA-1,4-DIEN-3-ONES; QUANTUM CHEMICAL CALCULATIONS; REACTION ENERGIES; REACTION MECHANISMS; SYNTHESIS OF; TRIFLUOROMETHANESULFONIC ACIDS;

CYCLIZATION;

5 ARYL 1 AZAPENTA 1,4 DIEN 3 ONE; BENZO[B]CYLOPENTAL[D]THIOPHENE; HYDRAZONE DERIVATIVE; OXIME DERIVATIVE; THIOPHENE DERIVATIVE; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; FLUORINE NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM CHEMISTRY; SYNTHESIS; X RAY DIFFRACTION;

EID: 56249137224     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-0028-1083188     Document Type: Article

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