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Volumn 47, Issue 19, 2008, Pages 9010-9020

Solution behavior and structural properties of Cu(I) complexes featuring m-terphenyl isocyanides

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Indexed keywords


EID: 54249158830     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8010986     Document Type: Article
Times cited : (71)

References (119)
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    • 6: R = Ph; Mann, K. R.; Cimolino, M.; Geoffroy, G. L.; Hammond, G. S.; Orio, A. A.; Albertin, G.; Gray, H. B. Inorg. Chim. Acta 1976, 16, 97-101;
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    • R = t-Bu. (a) Chiu, K. W.; Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1981, 2088-2097.
    • R = t-Bu. (a) Chiu, K. W.; Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1981, 2088-2097.
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    • For representative early accounts, see: a
    • For representative early accounts, see: (a) Irving, H.; Jonason, M. J. Chem. Soc. 1960, 2095-2097.
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    • Reference 25a reports several examples of (μ-X)2[Cu(CNR) 2]2 complexes X, Cl, X-ray diffraction experiments
    • 2 complexes (X = Cl, Br, I) proposed on the basis of powder X-ray diffraction experiments.
    • Br, I) proposed on the basis of powder
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    • 3]OTf is treated with LiCl.
    • 3]OTf is treated with LiCl.
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    • It is pertinent to note that model [Cu(CNArPh2) 3, optimized to a structure containing a planar Cu atom (Σ(∠Ciso-Cu-Ciso, 359.4°, Supporting Information, Figure S2-1, This observation lends credence to the notion that the presence of a C6H6 molecule perturbs the Cu coordination geometry in, η1-C-C6H 6)Cu(CNArMes2)3]OTf
    • 3]OTf.
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    • See Supporting Information
    • See Supporting Information.
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    • (2008) ADF-GUI 2007.01


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.