Synthesis of new bulky isocyanide ligands and their use for Rh-catalyzed hydrosilylation

Chemistry Letters

Volumn 35, Issue 9, 2006, Pages 1038-1039

  Ito, Hajime ^a   Kato, Takayuki ^a   Sawamura, Masaya ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33845277367     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2006.1038     Document Type: Article

References (25)

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18. 4 (6.1 mg, 0.015 mmol) and an isocyanide (0.015-0.045 mmol) were placed in a reaction tube. The tube was evacuated and backfilled with argon. After addition of anhydrous, degassed benzene (1.5 mL), the mixture was stirred at room temperature for 1 h. Cyclohexanone (147 mg, 1.5 mmol), 1,4-diisopropylbenzene (66.9 mg, 0.412 mmol, as an internal standard for GC analysis), and dimethylphenylsilane (245 mg, 1.8 mmol) were then added. The yield of product was determined by GC.
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