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0348128159
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note
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For complete experimental, spectroscopic, and crystallographic details, see the Supporting Information.
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24
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0346867655
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note
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2O was added dropwise. The color slowly changed to yellow, and after 45 min of stirring, the solution was filtered and concentrated to about 3 mL. Cooling (-35 °C) of the concentrated solution overnight yielded pure yellow crystals of 2 (108 mg, 0.132 mmol, 92%). Spectroscopic and analytical data are given in the Supporting Information.
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27
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0346237229
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note
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2) = 0.1441.
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28
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0037078698
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Nickel complexes with butterfly geometry are known for monomeric and polynuclear species: (a) Harrop, T. C.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chim. Acta 2002, 338, 189.
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Harrop, T.C.1
Olmstead, M.M.2
Mascharak, P.K.3
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0035847534
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(b) Uhl, W.; Melle, S.; Frenking, G.; Hartmann, M. Inorg. Chem. 2001, 40, 750.
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Inorg. Chem.
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Uhl, W.1
Melle, S.2
Frenking, G.3
Hartmann, M.4
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30
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1842403582
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(a) Bach, I.; Pörschke, K.-R.; Proft, B.; Goddard, R.; Kopiske, C.; Krüger, C.; Rufinska, A.; Seevogel, K. J. Am. Chem. Soc. 1997, 119, 3773.
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Bach, I.1
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Proft, B.3
Goddard, R.4
Kopiske, C.5
Krüger, C.6
Rufinska, A.7
Seevogel, K.8
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31
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4243181433
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(b) Bach, I.; Pörschke, K.-R.; Goddard, R.; Kopiske, C.; Krüger, C.; Rufinska, A.; Seevogel, K. Organometallics 1998, 15, 4959.
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Bach, I.1
Pörschke, K.-R.2
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Rufinska, A.6
Seevogel, K.7
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32
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0002549687
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Bach, I.; Pörschke, K.-R.; Goddard, R.; Kopiske, C.; Krueger, C.; Rufinska, A.; Seevogel, K. Organometallics 1999, 18, 10.
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Bach, I.1
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Goddard, R.3
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Rufinska, A.6
Seevogel, K.7
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33
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0346237228
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note
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2O solution of 2-butyne (42 mg, 0.776 mmol) was then added, and the solution was stirred for 30 min. The yellow-orange solution was then dried and extracted with petroleum ether, and the extract was filtered. cyclo-(dmp)PCMe=CMe was obtained by filtration of a petroleum ether solution through silica gel, concentrated to ca. 2 mL, and cooled to give pale yellow microcrystals (27 mg, 0.667 mmol, 56%).
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34
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0348128155
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note
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2) = 0.0795.
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35
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0000294275
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Edelbach, B. L.; Lachicotte, R. J.; Jones, W. D. Organometallics 1999, 18, 4040.
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Edelbach, B.L.1
Lachicotte, R.J.2
Jones, W.D.3
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36
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84863126297
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Pörschke, K.-R.; Pluta, C.; Proft, B.; Lutz, F.; Krüger, C. K. Z. Naturforsch., B: Anorg. Chem., Org. Chem. 1993, 48, 608.
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(1993)
Z. Naturforsch., B: Anorg. Chem., Org. Chem.
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Pörschke, K.-R.1
Pluta, C.2
Proft, B.3
Lutz, F.4
Krüger, C.K.5
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37
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0037139593
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Ehlers, A. W.; Baerends, E. J.; Lammertsma, K. J. Am. Chem. Soc. 2002, 124, 2831.
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Ehlers, A.W.1
Baerends, E.J.2
Lammertsma, K.3
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