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Volumn 45, Issue 36, 2006, Pages 5987-5991

Activation of aryl germanium(II) chlorides by [Mo(PMe3) 6] and [W(η2-CH2PMe2)H(PMe 3)4]: A new route to metal-germanium triple bonds

Author keywords

Germanium; Hydride ligands; Molybdenum; Multiple bonds; Tungsten

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL BONDS; COMPLEXATION; MOLECULAR STRUCTURE; REACTION KINETICS; TUNGSTEN;

EID: 33748802762     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200602061     Document Type: Article
Times cited : (67)

References (84)
  • 30
    • 33748800869 scopus 로고    scopus 로고
    • note
    • The term electron-rich metal center is used here to indicate the presence of filled metal-centered molecular orbitals at high energy in these complexes.
  • 41
    • 33748807347 scopus 로고    scopus 로고
    • 12) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 42
    • 85099527185 scopus 로고    scopus 로고
    • note
    • 6, respectively.
  • 43
    • 85099527540 scopus 로고    scopus 로고
    • see the Supporting Information
    • 4] (2-Mo-c) was isolated (see the Supporting Information).
  • 45
    • 85099527098 scopus 로고    scopus 로고
    • see the Supporting Information
    • 4] (2-Mo-c); see the Supporting Information).
  • 46
  • 48
    • 24444455961 scopus 로고
    • More common are insertions of germanium(II) halides in metal-heteroatom, metal-metal, or metal-hydrogen bonds: c) P. Rivière, J. Satgé, A. Boy, J. Organomet. Chem. 1975, 96, 25;
    • (1975) J. Organomet. Chem. , vol.96 , pp. 25
    • Rivière, P.1    Satgé, J.2    Boy, A.3
  • 53
    • 33748768593 scopus 로고    scopus 로고
    • note
    • 3 ligands (P1 and P3).
  • 60
    • 33748763722 scopus 로고    scopus 로고
    • note
    • The maximum deviation of the atoms W, Ge, P1, C1, P3, and H54 from the least-square plane is less than 10 pm.
  • 73
    • 33748763174 scopus 로고    scopus 로고
    • note
    • It is noticeable that the W-Ge triple-bond length of 4-W-H does not differ from those of 4-W-X (X = Cl, I), despite the presence of a hydrido ligand which exerts a strong irons influence. This finding suggests that the σ-bonding part of the W-Ge bond, which is expected to be weakened in 4-W-H by the hydrido ligand, has a minor influence on the W-Ge triple-bond length.
  • 74
    • 85099526468 scopus 로고    scopus 로고
    • note
    • -1 (Supporting Information).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.