Mechanism of alkane C-H bond activation by copper and silver homoscorpionate complexes

Organometallics

Volumn 25, Issue 22, 2006, Pages 5292-5300

  Braga, Ataualpa A C ^a   Maseras, Feliu ^a   Urbano, Juan ^b   Caballero, Ana ^b   Díaz Requejo, M Mar ^b   Pérez, Pedro J ^b  

^a INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^b Laboratorio de Catalisis Homogenea   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BUTANE; CHEMICAL ACTIVATION; COMPLEXATION; METHANE; ORGANOMETALLICS; REACTION KINETICS; SILVER;

BOND ACTIVATION; BOND FORMING PROCESSES; ENERGY BARRIER; METALLOCARBENE;

CHEMICAL BONDS;

EID: 84961975554     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060445h     Document Type: Article

References (29)

1. (a) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
2. (b) Shilov, A. E.; Shulpin, G. B. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes; Kluwer: Dordrecht, 2000.
3. (b) Dyker, G. Angew. Chem., Int. Ed. Engl. 1989, 28, 1698.
4. (c) Guari, Y.; Sabo-Etienne, S.; Chaudret, B. Eur. J. Inorg. Chem. 1999, 1047.
5. (d) Shilov, A. E.; Shulpin, G. B. Chem. Rev. 1997, 97, 2879.
6. (e) Arndtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154.
7. (a) Davies, H. M. L.; Beckwith, R. E. J. Chem. Rev. 2003, 103, 2861.
8. (b) Doyle, M. P.; McKervey, M. A.; Ye, T. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds; John Wiley & Sons: New York, 1998.
9. (c) Doyle, M. P. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, U.K., 1995; Vol. 12, p 421.
10. Pirrung, M. C.; Liu, H.; Morehead, A. T. J. Am. Chem. Soc. 2002, 124, 1014.
11. Nakamura, E.; Yoshikai, N.; Yamanaka, M. J. Am. Chem. Soc. 2002, 124, 7181.
12. Kirmse, W. Angew. Chem., Int. Ed. 2003, 42, 1088.
13. Díaz-Requejo, M. M.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. J. Am. Chem. Soc. 2002, 124, 896.
14. Caballero, A.; Díaz-Requejo, M. M.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. J. Am. Chem. Soc. 2003, 125, 1446.
15. Caballero, A.; Díaz-Requejo, M. M.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. Organometallics 2003, 22, 4145.
16. Urbano, J.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Díaz-Requejo, M. M.; Pérez, P. J. Organometallics 2005, 24, 1528.
17. (a) Dias, H. V. R.; Browning, R. G.; Richey, S. A.; Lovely, C. J. Organometallics 2004, 23, 1200.
18. (b) Dias, H. V. R.; Browning, R. G.; Richey, S. A.; Lovely, C. J. Organometallics 2005, 24, 5784.
19. Lee, C.; Parr, R. G.; Yang, W. Phys. Rev. B 1988, 37, 785.
20. Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
21. Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623.
22. Frisch, M. J.; et al. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
23. Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284.
24. Ehlers, A. W.; Böhme, M.; Dapprich, S.; Gobbi, A.; Höllwarth, A.; Jonas, V.; Köhler, K. F.; Stegmann, R.; Veldkamp, A.; Frenking, G. Chem. Phys. Lett. 1993, 208, 111.
25. Höllwarth, A.; Böhme, M.; Dapprich, S.; Ehlers, A. W.; Gobbi, A.; Jonas, V.; Köhler, K. F.; Stegmann, R.; Veldkamp, A.; Frenking, G. Chem. Phys. Lett. 1993, 208, 237.
26. Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; Defrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654.
27. Miertus, S.; Scrocco, E.; Tomasi, J. Chem. Phys. 1981, 55, 117.
28. Vreven, T.; Morokuma, K. J. Chem. Phys. 1999, 111, 8799.
29. Mealli, C.; Arcus, C. S.; Wilkinson, J. L.; Marks, T. J.; Ibers, J. A. J. Am. Chem. Soc. 1976, 98, 711.