High-throughput kinetic study of hydrogenation over palladium nanoparticles: Combination of reaction and analysis

Chemistry - A European Journal

Volumn 14, Issue 15, 2008, Pages 4657-4666

  Trapp, Oliver ^a   Weber, Sven K ^a   Bauch, Sabrina ^a   Bäcker, Tobias ^a   Hofstadt, Werner ^a   Spliethoff, Bernd ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Gas chromatography; Hydrogenation; Kinetics; Nanoparticles; Palladium

Indexed keywords

ABS RESINS; AMORPHOUS MATERIALS; CATALYSIS; CHEMICAL REACTIONS; CHROMATOGRAPHIC ANALYSIS; COLUMN CHROMATOGRAPHY; COPOLYMERIZATION; FUSED SILICA; GAS CHROMATOGRAPHY; GERMANIUM; HYDROGENATION; HYDROSILYLATION; MATRIX ALGEBRA; MICROCIRCULATION; NANOPARTICLES; NANOSTRUCTURED MATERIALS; NANOSTRUCTURES; ORGANOMETALLICS; PALLADIUM; PHASE SEPARATION; PLASTIC PRODUCTS; POLYMERS; RATE CONSTANTS; REACTION RATES; SEPARATION; SILANES; SILICA; SILICONES; THICK FILMS; THROUGHPUT;

ACTIVATION PARAMETERS; CHROMATOGRAPHIC STATIONARY PHASE; CONTACT TIMES; DI-METHYLSILOXANE; DIFFUSION CO-EFFICIENT; FILM STABILITY; FUSED-SILICA CAPILLARIES; GAS-LIQUID-SOLID; HIGH THROUGHPUTS; INNER DIAMETER; KINETIC STUDIES; KINETICS; MULTI-PHASE REACTION; PALLADIUM ACETATE; PALLADIUM NANOPARTICLES; POLY-SILOXANE; POLYSILOXANES; RATE MEASUREMENTS; REACTION GASES; REACTION RATE CONSTANTS; SELF-CATALYZED; STATION ARY PHASES; STATIONARY PHASE; TEMPERATURE-DEPENDENT;

GAS PERMEABLE MEMBRANES;

METAL NANOPARTICLE; ORGANOMETALLIC COMPOUND; PALLADIUM; SILOXANE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; DIFFUSION; HYDROGENATION; KINETICS; PARTICLE SIZE; SYNTHESIS; TIME;

DIFFUSION; HYDROGENATION; KINETICS; METAL NANOPARTICLES; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PALLADIUM; PARTICLE SIZE; SILOXANES; TIME FACTORS;

EID: 53849126519     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701780     Document Type: Article

References (87)

1. P. L. Hansen, J. B. Wagner, S. Helveg, J. R. Rostrup-Nielsen, B. S. Clausen, H. Topsoe, Science 2002, 295, 2053.
2. C. T. Campbell. Nature 2004, 432, 282.
3. a) L. Razon, R. Schmitz, Chem. Eng. Sci. 1986, 41, 1561;
4. b) F. C. Moates. M. Somani, J. Annamalai, J. T. Richardson, D. Luss, R. C. Willson. Ind. Eng. Chem. Res. 1996, 35, 4801;
5. c) A. Holzwarth. H.-W. Schmidt, W. F. Maier. Angew. Chem. 1998, 110, 2788;
6. Angew. Chem. Int. Ed. 1998, 37, 2644;
7. d) M. T. Reetz, M. H. Becker, K. M. Kühling, A. Holzwarth, Angew. Chem. 1998, 110, 2792;
8. Angew. Chem. Int. Ed. 1998, 37, 2647;
9. e) S. J. Taylor, P. J. Morken, Science 1998. 280, 267;
10. f) S. S. Lasko. R. J. Hendershol, J. Reed, Y. Fu, M.-F. Fellmann, G. Oskarsdottir, C. M. Snively. J. Lauterbach in High-Throughput Analysis: Spectroscopic Imaging in the Mid-Infrared Applied to High-Throughput Studies of Supported Catalyst Libraries (Eds.: R. A. Potyrailo, E. Amis), Kluwer Academic, New York, 2003, p. 77;
11. g) J. Klein. W. Stichert, W. Strehlau, A. Brenner, D. Demuth, S. A. Schunk, H. Hibst, S. Storck. Catal. Today 2003, 81, 329;
12. h) S. Cypes, A. Hagemeyer, Z. Hogan, A. Lesik, Comb. Chem. High Throughput Screening 2007, 10, 25.
13. S. M. Senkan. S. Ozturk, Angew. Chem. 1999, 111, 867:
14. Angew. Chem. Int. Ed. 1999, 38, 791.
15. a) P. Cong, R. D. Doolen, Q. Fan, D. M. Giaquinta. S. Guan, E. W. Mcfarland, D. M. Poojary, K. Self, H. W. Turner, W. H. Weinberg, Angew. Chem. 1999, 111, 507;
16. Angew. Chem. Int. Ed. 1999, 38, 483;
17. b) M. Orschel. J. Klein, H.-W. Schmidt, W. F. Maier, Angew. Chem. 1999, 111, 2961;
18. Angew. Chem. Int. Ed. 1999, 38, 2791;
19. c) S. Senkan, K. Krantz, S. Ozturk, V. Zengin, I. Onal. Angew. Chem. 1999, 111, 2965;
20. Angew. Chem. Int. Ed. 1999, 38, 2794;
21. d) M.-J. Kang, A. Tholey. E. Heinzle, Rapid Commun. Mass Spectrom. 2001, 15, 1327;
22. e) H. Wang, Z. Liu, J. Shen, J. Comb. Chem. 2003, 5, 802.
23. a) A. C. Cooper, L. H. McAlexander, D.-H. Lee, M. T. Torres, R. H. Crabtree, J. Am. Chem. Soc. 1998, 120, 9971;
24. b) E. Reddington, A. Sapienza, B. Gurau, R. Viswanathan, S. Sarangapani, E. S. Smotkin, T. E. Mallouk. Science 1998, 280, 1735.
25. a) M. T. Reetz, A. Zonta, K. Schimossek, K. Liebeton, K.-E. Jaeger, Angew. Chem. 1997, 109, 2961:
26. Angew. Chem. Int. Ed. Engl. 1997, 36, 2830;
27. b) M. T. Reetz, K.-E. Jaeger. Top. Curr. Chem. 1999, 200, 31;
28. c) M. T. Reetz, K.-E. Jaeger, Chem. Eur. J. 2000, 6, 407;
29. d) P. G. Schultz, R. A. Lerner, Science 1995, 269, 1835;
30. e) F. Zocher, M. M. Enzelberger, U. T. Bornscheuer. B. Hauer, R. D. Schmid, Anal. Chim. Acta 1999, 391, 345;
31. f) E. Henke, U, T. Bornscheuer, Biol. Chem. 1999, 380, 1029.
32. a) A. P. de Silva, H. Q. N. Gunaratne, T. Gunnlaugsson. A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, T. E. Rice, Chem. Rev. 1991, 97, 1515;
33. b) G. Zandonella, L. Haalck, F. Spener. K. Faber, F. Paltauf, A. Hermetter, Chirality 1996, 8, 481;
34. c) G. Gauglitz, Curr. Opin. Chem. Biol. 2000, 4, 351;
35. d) M. Olsen, B. Iverson, G. Georgiou, Curr. Opin. Biotechnol. 2000, 11, 331;
36. e) R. P. Hertzberg, A.J. Pope. Curr. Opin. Chem. Biol. 2000, 4, 445.
37. C. Hoffmann, A. Wolf. F. Schüth, Angew. Chem. 1999, 111, 2971;
38. Angew. Chem. Int. Ed. 1999, 38, 2800.
39. R. A. Potyrailo, R. J. May, Rev. Sci. Instrum. 2002, 73, 1277.
40. O. Trapp, J. Chromatogr. A 2008, 1184, 160-190.
41. S. J. Haswell, P. Watts, Green Chem. 2003, 5, 240.
42. a) C. de Bellefon, N. Tanchoux, S. Caravieilhes, P. Grenouillet. V. Hessel, Angew. Chem. 2000, 112, 3584;
43. Angew. Chem. Int. Ed. 2000, 39. 3442;
44. b) J. Knight, Nature 2002, 418, 474;
45. c) A. Müller, K. Drese, H. Gnaser, M. Hampe, V. Hessel, H. Löwe. S. Schmitt, R. Zapf, Catal. Today 2003, 81, 377;
46. d) K. Jähnisch, V. Hessel, H. Löwe, M. Baerns, Angew. Chem. 2004, 116, 410;
47. Angew. Chem. Int. Ed. 2004, 43, 406;
48. e) D. Beider, M. Ludwig, L.-W. Wang, M. T Reetz, Angew. Chem. 2006, 118, 2523;
49. Angew. Chem. Int. Ed. 2006, 45, 2463;
50. f) D. Janasek, J. Franzke, A. Manz, Nature 2006, 442, 374;
51. g) S. J. Haswell, Nature 2006, 441, 705.
52. O. Trapp, S. K. Weber, S. Bauch, W. Hofstadl, Angew. Chem. 2007, 119. 7447:
53. Angew. Chem. Int. Ed. 2007, 46, 7307.
54. M. R. Arnold, Chem. Eng. Rev. 1956, 48, 1629.
55. a) H. Bönnemann, W. Brijoux. R. Brinkmann, E. Dinjus, T. Joujen, B. Korall, Angew. Chem. 1991, 103, 1344;
56. Angew. Chem. Int. Ed. Engl. 1991, 30, 1312;
57. b) M. T. Reetz, W. Helbig, S. A. Quaiser, U. Stimming, N. Breuer, R. Vogel. Science 1995, 267, 367;
58. c) H. Bönnemann, G. A. Braun, Angew. Chem. 1996, 108, 2120;
59. Angew. Chem. Int. Ed. Engl. 1996, 35, 1992;
60. d) H. Bönnemann. R. M. Richards, Eur. J. Inorg. Chem. 2001, 2455.
61. a) J. Kobayashi, Y. Mori, K. Okamoto, R. Akiyama. M. Ueno, T. Kitamori, S. Kobayashi, Science 2004, 304, 1305;
62. b) D. Astruc. F. Lu, J. R. Aranzaes, Angew. Chem. 2005, 117, 8062;
63. Angew. Chem. Int. Ed. 2005, 44, 7852.
64. a) M. T. Reetz, E. Westermann, Angew. Chem. 2000, 112, 170;
65. Angew. Chem. Int. Ed. 2000, 39, 165;
66. b) M. T. Reetz, J. G. D. Vries, Chem. Commun. 2004, 1559;
67. c) D. Astruc. Inorg. Chem. 2007, 46, 1884;
68. d) K. Köhler, W. Kleist, S. S. Pröckl, Inorg. Client. 2007, 46, 1876.
69. D. Teschner. E. Vass, M. Hävecker, S. Zafeiratos, P. Schnörch, H. Sauer, A. Knop-Gericke, R. Schlögl, M. Chamam, A. Wootsch, A. S. Canning, J. J. Gamman. S. D. Jackson, J. Mcgregor. L. F. Gladden, J. Catal. 2006, 242, 26.
70. B. P. S. Chauhan, J. S. Rathore, T. Bandoo, J. Am. Chem. Soc. 2004, 126, 849.
71. H. Figge, A. Deege, J. Köhler. G. Schomburg, J. Chromatogr. 1986, 351, 393.
72. W. Lu, B. Wang, K. Wang, X. Wang, J. G. Hou, Langmuir 2003, 19, 5887.
73. K. Grob, Making and Manipulating Capillary Columns for Gas Chromatography, Huethig, Heidelberg (Germany). 1986.
74. a) T. Falk, A. S. -Morgenstern, Chem. Eng. Sci. 1999, 54, 1479:
75. b) T. D. Vu, A. Seidel-Morgenstern, S. Grüner. A. Kienle, Ind. Eng. Chem. Res. 2005, 44, 9565.
76. A. Seidel-Morgenstern, J. Chromatogr. A 2004, 1037, 255.
77. a) T. Haas, J. Gaube, Chem. Eng. Technol. 1989, 12, 45;
78. b) M. Di Serio, V. Balato. A. Dimiccoli, L. Maffucci, P. Iengo, E. Santacesaria, Catal. Today 2001, 66, 403;
79. c) A. Schmidt, R. Schomäcker, Ind. Eng. Chem. Res. 2007, 46, 1677.
80. a) H. Wieland, Chem. Ber. 1912, 45, 484;
81. b) N. Zelinsky, N. Pavlov, Chem. Ber. 1923, 56B, 1249;
82. c) R. P. Linslead, S. L. S. Thomas, J. Chem. Soc. 1940, 1127.
83. a) J. J. vanDeemter, Ind. Eng. Chem. 1953, 45, 1227;
84. b) J. J. van Deemter, Ind. Eng. Chem. 1954, 46, 2300;
85. c) J. J. van Deemter, F. J. Zuiderweg, A. Klinkenberg, Chem. Eng. Sci. 1956, 5, 271;
86. d) J. J. van Deemter, Chem. Eng. Sci. 1961, 13, 143;
87. e) S. J. Hawkes, J. Chem. Educ. 1983, 60, 393.