High-throughput synthesis and screening of combinatorial heterogeneous catalyst libraries

Angewandte Chemie - International Edition

Volumn 38, Issue 4, 1999, Pages 483-488

  Cong, Peijun ^a   Doolen, Robert D ^a   Fan, Qun ^a   Giaquinta, Daniel M ^a   Guan, Shenheng ^a   McFarland, Eric W ^a   Poojary, Damodara M ^a   Self, Kyle ^a   Turner, Howard W ^a   Weinberg, W Henry ^a  

^a SYMYX TECHNOLOGIES   (United States)

Author keywords

Combinatorial chemistry; Heterogeneous catalysis; Mass spectrometry; Screening methods

Indexed keywords

CATALYST; MASS SPECTROMETRY; SYNTHESIS;

ARTICLE; CATALYSIS; CHEMICAL REACTION; MASS SPECTROMETRY; SYNTHESIS;

EID: 0033557815     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19990215)38:4<483::aid-anie483>3.3.co;2-r     Document Type: Article

References (22)

1. X.-D. Xiang, X. Sun, G. Briceno, Y. Lou, K.-A. Wang, H. Chang, W. G. Wallace-Freedman, S.-W. Chen, P. G. Schultz, Science 1995, 268, 1738-1740.
2. G. Briceno, H. Chang, X.-D. Sun, P. G. Schultz, X.-D. Xiang, Science 1995, 270, 273-275.
3. X.-D. Sun, K.-A. Wang, Y. Yoo, W. G. Wallace-Freedman, C. Gao, X.-D. Xiang, P. G. Schultz, Adv. Mater. 1997, 9, 1046-1049.
4. J. Wang, Y. Young, C Gao, I. Takeuchi, X. Sun, H. Chang, X.-D. Xiang, P. G. Schultz, Science 1998, 279, 1712-1714.
5. E. Danielson, J. H. Golden, E. W. McFarland, C. M. Reaves, W. H. Weinberg, X. D. Wu, Nature 1997, 389, 944-948.
6. E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, X. D. Wu, Science 1998, 279, 837-839.
7. F. C. Moates, M. Somani, J. Annamalai, J. T. Richardson, D. Luss, R. C. Wilson, Ind. Eng. Chem. Res. 1996, 55, 4801-4803. A related patent application (PCT US 97/02756) is broader in scope, but of less interest since no experiments were run.
8. S. M. Senkan, Nature 1998, 394, 350-352.
9. A. Holzwarth, H.-W. Schmidt, W. F. Maier, Angew. Chem. 1998, 110, 2788-2792;
10. Angew. Chem. Int. Ed. 1998, 37, 2644-2647.
11. T. Engel, G. Ertl, Adv. Catal. 1979, 28, 1-78.
12. K. C. Taylor, Ind. Eng. Chem. Prod. Res. Dev. 1976, 15, 264-268.
13. R. M. Heck, R. J. Farrauto, Catalytic Air Pollution Control: Commercial Technology, Van Nostrand Reinhold, New York, 1995.
14. α radiation (2-kW generator, λ= 1.5418 Å) in the range 10 < 20 < 72° with an exposure time of 10 min per catalyst. The primary beam was focussed to a spot of 700 μm in diameter by means of bent Göbel mirrors and a collimator. The library was mounted on the XYZ stage of the diffractometer and initial alignments were carried out with a laser and video microscope assembly.
15. W. H. Weinberg, E. W. McFarland, P. Cong, S. Guan (Symyx Technologies), WO-A 98/15969 A2, 1998.
16. J. A. Rodriguez, D. W. Goodman, Surf. Sci. Rep. 1991, 14, 1-107.
17. J. Szanyi, D. W. Goodman, J. Catal. 1994, 145, 508-515.
18. R. E. R. Colen, M. Kolodziejczyk, B. Delmon, J. H. Block, Surf. Sci. 1998, 412, 447-457.
19. R. W. Vook, B. Oral, Appl. Surf. Sci. 1992, 60, 681-687.
20. W. F. Egelhoff, Jr. in The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis, Vol. 4 (Eds.: D. A. King, D. P. Woodruff), Elsevier, Amsterdam, 1982, pp. 397-426.
21. K. C. Taylor, Stud. Surf. Sci. Catal. 1987, 30, 97-116.
22. S. M. Vesecky, P. Chen, X. Xu, D. W. Goodman, J. Vac. Sci. Technol. A 1995, 13, 1539-1543.