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Volumn , Issue 13, 2008, Pages 2137-2142

Hydrothermal synthesis and structural characterization of the high-valent ruthenium-containing polyoxoanion [{PW11O39} 2{(HO)RuIV-O-RuIV(OH)}]10-

Author keywords

Polyoxometalates; Raman spectroscopy; Ruthenium; Tungsten

Indexed keywords

HYDROTHERMAL SYNTHESIS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; TUNGSTEN; X RAY DIFFRACTION;

EID: 53249131028     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701359     Document Type: Article
Times cited : (22)

References (80)
  • 3
    • 3442886712 scopus 로고    scopus 로고
    • J. J. Borras-Almenar, E. Coronado, A. Müller, M. T. Pope Eds, Kluwer Academic Publisher, Dordrecht
    • J. J. Borras-Almenar, E. Coronado, A. Müller, M. T. Pope (Eds.), Polyoxometalate Molecular Science, Kluwer Academic Publisher, Dordrecht, 2003.
    • (2003) Polyoxometalate Molecular Science
  • 49
    • 85163223617 scopus 로고    scopus 로고
    • Ph. D. Thesis, Université Pierre et Marie Curie Paris VI Paris
    • D. Laurencin, Ph. D. Thesis, Université Pierre et Marie Curie Paris VI (Paris), 2006.
    • (2006)
    • Laurencin, D.1
  • 61
    • 85163230809 scopus 로고    scopus 로고
    • These values have been obtained from Bond Valence Sum (BVS) calculations where BVS, ΣBVi, Σexp[(r0, r i)/B, B, 0.37 and r0, 1.834 Å for RuIV-O2, see ref.[64, However, this r0 value appears to be overestimated (see ref, 65, and the calculated valences for both Ru should be closer to +4. For instance, in the case of Finke's complex, α2-P 2W17O61}2{Cl2Ru IV2(μ-O, 16, see ref.[16, we found BVS, 4.64 for the RuIV ion with this set of data r 0, 2.21 for RuIV-Cl, see ref, 64
    • [64]).
  • 62
    • 0004290489 scopus 로고
    • Eds, M. O'Keeffe, A. Navrotsky, Academic Press, New York
    • I. D. Brown, in Structure and Bonding in Crystals (Eds.: M. O'Keeffe, A. Navrotsky), Academic Press, New York, 1981.
    • (1981) Structure and Bonding in Crystals
    • Brown, I.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.