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Volumn 42, Issue 10, 2003, Pages 3331-3339

Preparation and characterization of new ruthenium and osmium containing polyoxometalates, [M(DMSO)3Mo7O24]4- (M = Ru(II), Os(II)), and their use as catalysts for the aerobic oxidation of alcohols

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; ALDEHYDE; DIMETHYL SULFOXIDE; HEPTAMOLYBDATE POLYOXOMETALATE; KETONE; METAL DERIVATIVE; MOLYBDENUM; OSMIUM; OXYGEN; RUTHENIUM; SULFUR; UNCLASSIFIED DRUG;

EID: 0037616173     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic026003p     Document Type: Article
Times cited : (83)

References (108)
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    • Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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    • Boesing, M.1    Noeh, A.2    Loose, I.3    Krebs, B.4
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    • 0000304427 scopus 로고    scopus 로고
    • Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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    • Zhang, X.1    Chen, Q.2    Duncan, D.C.3    Lachicotte, R.J.4    Hill, C.L.5
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    • note
    • 40 gave no MW/z peaks but instead a much more complicated and difficult to analyze and understand fragmentation pattern.
  • 102
    • 0037689761 scopus 로고    scopus 로고
    • note
    • An alternative explanation as suggested by a referee could be that a small amout of the catalyst is oxidized to a ruthenium or osmium(III) species that is in fact the active catalyst. While this possibility remains, we have observed that the original brown compounds and solutions are in fact (partially) reduced during the catalytic cycle to yield a green solution typical of molybdenum containing polyoxometalates. At the completion of the reaction, the original brown solutions are recovered.
  • 103
    • 0037689760 scopus 로고    scopus 로고
    • note
    • The Hammett relationship observed also points against the possibility of a reaction initiated by electron transfer since in such a case a negative p value would also be expected for all substituents considering the much higher oxidation potential of. for example, nitro substituted substrates.


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