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0033989142
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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91
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33751158644
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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93
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37049085618
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Both FAB-MS (refs 24b-h) and MALDITOF-MS (ref 24a) have been occasionally used in polyoxometalate research; however, there has been no general study on the use of mass spectrometry in the polyoxometalate field. (a) Mayer, C. R.; Fournier, I.; Thouvenot, R. Chem. Eur. J. 2000, 6, 105. (b) Finke, R. G.; Droege, M. G.; Cook, J. C.; Suslick, K. S. J. Am. Chem. Soc. 1984, 106, 5750. (c) Suslick, K. S.; Cook, J. C.; Rapko, B.; Droege, M. W.; Finke, R. G. Inorg. Chem. 1986, 25, 241. (d) Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3625. (e) Liu, J.; Ortega, F.; Sethuraman, P.; Katsoulis, D. E.; Costello, C. E.; Pope, M. T. J. Chem. Soc., Dalton Trans. 1992, 1901. (f) Judeinstein, P.; Deprun, C.; Nadjo, L. J. Chem. Soc., Dalton Trans. 1991, 1991. (g) Boesing, M.; Noeh, A.; Loose, I.; Krebs, B. J. Am. Chem. Soc. 1998, 120, 7252. (h) Zhang, X.; Chen, Q.; Duncan, D. C.; Lachicotte, R. J.; Hill, C. L. Inorg. Chem. 1997, 36, 4381.
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Hill, C.L.5
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96
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0037689762
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note
-
40 gave no MW/z peaks but instead a much more complicated and difficult to analyze and understand fragmentation pattern.
-
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97
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0001076904
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McCarron, E. M., III; Whitney, J. F.; Chase, D. B. Inorg. Chem. 1984, 23, 3275.
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0034673313
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102
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0037689761
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note
-
An alternative explanation as suggested by a referee could be that a small amout of the catalyst is oxidized to a ruthenium or osmium(III) species that is in fact the active catalyst. While this possibility remains, we have observed that the original brown compounds and solutions are in fact (partially) reduced during the catalytic cycle to yield a green solution typical of molybdenum containing polyoxometalates. At the completion of the reaction, the original brown solutions are recovered.
-
-
-
-
103
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0037689760
-
-
note
-
The Hammett relationship observed also points against the possibility of a reaction initiated by electron transfer since in such a case a negative p value would also be expected for all substituents considering the much higher oxidation potential of. for example, nitro substituted substrates.
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105
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0035812358
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(b) Khenkin, A. M.; Weiner, L.; Wang, Y.; Neumann, R. J. Am. Chem. Soc. 2001, 123, 8531
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Antonov, P. G.; Kukushkin, Y. N.; Konnov, V. I.; Kostokov, Y. P. Koord. Khim. 1980, 6, 1585.
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Kostokov, Y.P.4
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