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Volumn , Issue 18, 2008, Pages 2863-2873

A modular approach towards nonsymmetrical bis(metallosalen) building blocks

Author keywords

N,O ligands; Salen ligands; Supramolecular chemistry; Zinc

Indexed keywords

DIHEDRAL ANGLE; LIGANDS; ZINC COMPOUNDS;

EID: 53249088112     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800274     Document Type: Article
Times cited : (25)

References (56)
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    • For reviews, see: a, Eds: E. W. Abel, F. G. A. Stone, E. Willinson, Pergamon, New York
    • For reviews, see: a) E. N. Jacobsen in Comprehensive Organometallic Chemistry II (Eds: E. W. Abel, F. G. A. Stone, E. Willinson), Pergamon, New York, 1995, vol. 12, pp. 1097-1135;
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 1097-1135
    • Jacobsen, E.N.1
  • 6
    • 0037288744 scopus 로고    scopus 로고
    • f) T. Katsuki, Synlett 2003, 3, 281-297;
    • (2003) Synlett , vol.3 , pp. 281-297
    • Katsuki, T.1
  • 23
    • 7644235766 scopus 로고    scopus 로고
    • See for instance: a
    • See for instance: a) P. G. Cozzi, Chem. Soc. Rev. 2004, 33, 410-421;
    • (2004) Chem. Soc. Rev , vol.33 , pp. 410-421
    • Cozzi, P.G.1
  • 32
    • 85163234074 scopus 로고    scopus 로고
    • A preliminary account of this work was recently published: S. Curreli, E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, J. Org. Chem. 2007, 72, 7018-7021.
    • A preliminary account of this work was recently published: S. Curreli, E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, J. Org. Chem. 2007, 72, 7018-7021.
  • 37
    • 85163232830 scopus 로고    scopus 로고
    • II salphens in adsorption of alkaloids, see: e E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2008, 47, 4256-4263;
    • II salphens in adsorption of alkaloids, see: e) E. C. Escudero-Adán, J. Benet-Buchholz, A. W. Kleij, Inorg. Chem. 2008, 47, 4256-4263;
  • 41
    • 41049086532 scopus 로고    scopus 로고
    • For some recent examples of cooperative bimetallic salen-based catalysis, see: a
    • For some recent examples of cooperative bimetallic salen-based catalysis, see: a) C. Mazet, E. N. Jacobsen, Angew. Chem. Int. Ed. 2008, 47, 1762-1765;
    • (2008) Angew. Chem. Int. Ed , vol.47 , pp. 1762-1765
    • Mazet, C.1    Jacobsen, E.N.2
  • 44
    • 85163224703 scopus 로고    scopus 로고
    • We use the term nonsymmetrical here to designate the symmetry within each salen unit
    • We use the term "nonsymmetrical" here to designate the symmetry within each salen unit.
  • 45
    • 85163234425 scopus 로고    scopus 로고
    • Here, the isomer with the highest symmetry is isolated, which relates to the exo-exo compound.
    • Here, the isomer with the highest symmetry is isolated, which relates to the exo-exo compound.
  • 46
    • 85163224757 scopus 로고    scopus 로고
    • Crystal data for compound 26: Formula 2(C52H 50N8O14S2Zn2) ·7(C2H6OS, M, 2958.81, monoclinic, C2/c (No. 15, a, 36.4392(10) Å, b, 9.5882(3) Å, c, 38.4521(11) Å, β, 99.921(1)°, V, 13233.7(7) Å3, Z, 4, ρcalcd, 1.485 g/cm3, F(000, 6152, crystal size 0.15 x 0.20 x 0.30 mm, T, 100 K, θmin-max, 2.7-35.8°, total/unique data, 34311/18891, Rint, 0.046, observed data [I > 2.0σI, 12770, Nref/Npar, 18891/894, R/wR/S, 0.0588/0.1607/1.03, max. and av. shift/error, 0.00, 0.00, min. and max. resd. dens, 0.74, 1.88 e/Å3
    • 3.
  • 47
    • 85163225653 scopus 로고    scopus 로고
    • Crystal data for compound 30: Formula (C60H 66N8O14S2Zn2) ·12(C2H6OS)·(C2H 6OS)·2(H2O, M, 3688.09, triclinic, P1 (No. 2, a, 14.7497(9) Å, b, 16.5770(9) Å, c, 19.9117(12) Å, α, 79.456(3)°, β, 74.018(3)o, γ, 73.347(3)°, V, 4455.3(5) Å3, Z, 1, ρcalcd, 1.375 g/cm3, F(000, 1938, crystal size 0.10 x 0.20 x 0.30 mm, T, 100 K, θmin-max, 2.6-31.3°, total/unique data, 65510/26748, Rint, 0.052, observed data [I > 2.0σI, 17287, N ref/Npar, 26748/1069, R/wR/S, 0.0855/0.2670/1.03, max. and av. shift/error, 0.00, 0.00, min. and max. resd. dens, 3.31, 2.50 e/Å3
    • 3.
  • 48
    • 85163230883 scopus 로고    scopus 로고
    • Crystal data for compound 31·bipy: Formula (C 33H31Cl2N3O2Zn) ·5(C4H8O, M, 998.42, triclinic, P1 (No. 2, a, 9.6480(6) Å, b, 16.1632(9) Å, c, 17.5764(9) Å, α, 87.570(3)°, β, 74.285(3)°, γ, 74.177(3)°, V, 2537.0(3) Å3, Z, 2, ρcalcd, 1.307 g/cm3, F(000, 1060, crystal size 0.05 x 0.05 x 0.40 mm, T, 100 K, θmin-max, 2.8-30.9°, total/unique data, 23805/13472, Rint= 0.048, observed data [I > 2.0σI, 9787, N ref/Npar, 13472/696, R/wR/S, 0.0696/0.2116/1.04, max. and av. shift/error, 0.00, 0.00, min. and max. resd. dens, 1.21, 2.00 e/Å3
    • 3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.