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Volumn 11, Issue 16, 2005, Pages 4743-4750

ZnII-salphen complexes as versatile building blocks for the construction of supramolecular box assemblies

Author keywords

Molecular boxes porous materials; Self assembly; Supramolecular chemistry; Zinc

Indexed keywords

NANOSTRUCTURED MATERIALS; ORGANIC ACIDS; PHASE TRANSITIONS; SCANNING ELECTRON MICROSCOPY; SELF ASSEMBLY; SUPRAMOLECULAR CHEMISTRY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 23744473315     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200500227     Document Type: Article
Times cited : (180)

References (64)
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    • Salen ligands/complexes appended with pyridine groups at the 3 and 3′ positions have been recently used to construct loop- and square-type assemblies. The major difference with respect to the current approach is that in these studies the metal center of the salphen unit was not used to induce assembly formation. See: a) K. E. Splan, A. M. Massari, G. A. Morris, S.-S. Sun, E. Reina, S. T. Nguyen, J. T. Hupp, Eur. J. Inorg. Chem. 2003, 2348-2351;
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    • note
    • Please note that the isolation of the precursor ligands is not necessary with this approach and that asymmetrically substituted salphen-Zn complexes can be readily accessed.
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    • We examined the binding curves in the present studies with software developed by Prof. C. A. Hunter (Sheffield University, UK). See also: A. P. Bisson, C. A. Hunter, J. C. Morales, K. Young, Chem. Eur. J. 1998, 4, 845-851.
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    • note
    • II-salphen complexes in this work proved to be unstable in the presence of relatively acidic solvents such as [D]chloroform.
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    • note
    • 3. Note that the asterisk behind some of the numerical, crystallographic data denote the values without the contribution of the disordered solvent molecules.
  • 47
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    • 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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    • The slow-exchange region was not reached and must be below -60°C
    • The slow-exchange region was not reached and must be below -60°C.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.