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While the O-Zn-O angles in (1)2·[(dmpy) 2Zn] are comparable to those found in the (dmpy)2Zn(sac) 2 complex (see ref 8, the N-Zn-N angle of 143.03° is significantly different from the same angle found in the latter complex 173.74°
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2 complex (see ref 8), the N-Zn-N angle of 143.03° is significantly different from the same angle found in the latter complex (173.74°).
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3 assembly.
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3 assembly.
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2Zn]. These results suggest that the templated formation of these assemblies may be reversible. This was further corroborated by the fact that signal integration of the original batch of mixed crystals afforded exactly an equimolar ratio between all salphen and all dmpy components.
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2Zn]. These results suggest that the templated formation of these assemblies may be reversible. This was further corroborated by the fact that signal integration of the original batch of mixed crystals afforded exactly an equimolar ratio between all salphen and all dmpy components.
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For the use of interesting Zn-centered salen templating derivatives, see: a
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For the use of interesting Zn-centered salen templating derivatives, see: (a) Gallant, A. J.; Chong, J. H.; MacLachlan, M. J. Inorg. Chem. 2006, 45, 5248.
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