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For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
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For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
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For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
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10444237879
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note
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1/c; unit cell a = 9.949(2) Å, b = 24.138(5) Å, c = 8.1414(16) Å, β= 108.54(3)°; determined at 213(2) K; R1 (wR2) = 0.0796 (0.1077) for all data. Selected bond distances (Å), bond angles (deg), and torsion angles (deg): Si1-N1 = 1.733(2), Si1-N2 = 1.748(2), Si1-C1 = 1.860-(3), Si1-Si2 = 2.358(1); N1-Si1-N2 = 93.5(1), Cl-Si1-Si2 = 110.8-(1); Si1-N1-C3-C4 = 26.9(4), Si1-N2-C11-C12 = 30.2(4).
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17
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10444222928
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note
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1/c; unit cell a = 10.522(3) Å, b = 17.006(4) Å, c = 22.655-(6) Å, β= 101.420(4)°; determined at 213(2) K; R1 (wR2) = 0.0759 (0.1198) for all data. Selected bond distances (Å) and angles (deg): Si1-N1 = 1.992(2), Si1-N2 = 1.740(2), Si1-O1 = 1.708(2), Si1-O2 = 1.709(2), Si1-C31 = 1.876(3), Si2-C22 = 1.947(3), Si2-C32 = 1.859-(3), N1-C7 = 1.295(3), N2-C22 = 1.511(3); N1-Si1-O2 = 179.2(1), O1-Si1-N2 = 116.8(1), C31-Si1-N2 = 127.2(1), O1-Si1-C31 = 114.5(1).
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18
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0036260064
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22
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0009493076
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For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
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Kabeta, K.1
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23
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84982454585
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For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
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Rengstl, A.1
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24
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0001633552
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For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
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