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Volumn 23, Issue 25, 2004, Pages 6066-6069

Activation of a Si-Si bond by hypercoordination: Cleavage of a disilane and formation of a Si-C bond

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHELATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICON; X RAY ANALYSIS;

EID: 10444242691     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om040096w     Document Type: Article
Times cited : (41)

References (30)
  • 5
    • 0000901365 scopus 로고    scopus 로고
    • For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
    • (1997) Synlett , pp. 693-694
    • Mori, A.1    Fujita, A.2    Ikegashira, K.3    Nishihara, Y.4    Hijama, T.5
  • 6
    • 0001513634 scopus 로고
    • For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
    • (1992) Organometallics , vol.11 , pp. 2353-2355
    • Tsuji, Y.1    Lago, R.M.2    Tomohiro, S.3
  • 7
    • 0010241882 scopus 로고
    • For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
    • (1992) Organometallics , vol.11 , pp. 483-484
    • Ishikawa, M.1    Nishimura, Y.2    Sakamoto, H.3    Ono, T.4    Ohshita, J.5
  • 8
    • 0001313094 scopus 로고
    • For 1,4-addition reactions of disilanes to 1,3-dienes see e.g.: (a) Mori, A.; Fujita, A.; Ikegashira, K.; Nishihara, Y.; Hijama, T. Synlett 1997, 693-694. (b) Tsuji, Y.; Lago, R. M.; Tomohiro, S. Organometallics 1992, 11, 2353-2355. Ishikawa, M.; Nishimura, Y.; Sakamoto, H.; Ono, T.; Ohshita, J. Organometallics 1992, 11, 483-484. Hiyama, T.; Obayashi, M.; Mori, I.; Nozaki, H. J. Org. Chem. 1983, 48, 912-914.
    • (1983) J. Org. Chem. , vol.48 , pp. 912-914
    • Hiyama, T.1    Obayashi, M.2    Mori, I.3    Nozaki, H.4
  • 15
    • 10444237879 scopus 로고    scopus 로고
    • note
    • 1/c; unit cell a = 9.949(2) Å, b = 24.138(5) Å, c = 8.1414(16) Å, β= 108.54(3)°; determined at 213(2) K; R1 (wR2) = 0.0796 (0.1077) for all data. Selected bond distances (Å), bond angles (deg), and torsion angles (deg): Si1-N1 = 1.733(2), Si1-N2 = 1.748(2), Si1-C1 = 1.860-(3), Si1-Si2 = 2.358(1); N1-Si1-N2 = 93.5(1), Cl-Si1-Si2 = 110.8-(1); Si1-N1-C3-C4 = 26.9(4), Si1-N2-C11-C12 = 30.2(4).
  • 17
    • 10444222928 scopus 로고    scopus 로고
    • note
    • 1/c; unit cell a = 10.522(3) Å, b = 17.006(4) Å, c = 22.655-(6) Å, β= 101.420(4)°; determined at 213(2) K; R1 (wR2) = 0.0759 (0.1198) for all data. Selected bond distances (Å) and angles (deg): Si1-N1 = 1.992(2), Si1-N2 = 1.740(2), Si1-O1 = 1.708(2), Si1-O2 = 1.709(2), Si1-C31 = 1.876(3), Si2-C22 = 1.947(3), Si2-C32 = 1.859-(3), N1-C7 = 1.295(3), N2-C22 = 1.511(3); N1-Si1-O2 = 179.2(1), O1-Si1-N2 = 116.8(1), C31-Si1-N2 = 127.2(1), O1-Si1-C31 = 114.5(1).
  • 22
    • 0009493076 scopus 로고
    • For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
    • (1991) Organometallics , vol.10 , pp. 827
    • Kabeta, K.1    Powell, D.R.2    Hanson, J.3    West, R.4
  • 23
    • 84982454585 scopus 로고
    • For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
    • (1980) Chem. Ber. , vol.113 , pp. 278
    • Rengstl, A.1    Schubert, U.2
  • 24
    • 0001633552 scopus 로고    scopus 로고
    • For examples of long Si-C bonds, see: (a) Kabeta, K.; Powell, D. R.; Hanson, J.; West, R. Organometallics 1991, 10, 827. (b) Rengstl, A.; Schubert, U. Chem. Ber. 1980, 113, 278. Dakternieks, D.; Jurkschat, K.; Tozer, R.; Hook, J.; Tiekink, E. R. T. Organometallics 1997, 16, 3696.
    • (1997) Organometallics , vol.16 , pp. 3696
    • Dakternieks, D.1    Jurkschat, K.2    Tozer, R.3    Hook, J.4    Tiekink, E.R.T.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.