Stereoselective synthesis of highly enantioenriched (E)-allylsilanes by palladium-catalyzed intramolecular bis-silylation: 1,3-chirality transfer and enantioenrichment via dimer formation

Chemistry - A European Journal

Volumn 11, Issue 10, 2005, Pages 2954-2965

  Suginome, Michinori ^a,b,c   Iwanami, Taisuke ^a   Ohmori, Yutaka ^a   Matsumoto, Akira ^a   Ito, Yoshihiko ^a  

^a KYOTO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c DOSHISHA UNIVERSITY   (Japan)

Author keywords

Asymmetric synthesis; Dimerization; Palladium catalyst; Silicon; Silylation

Indexed keywords

ALCOHOLS; CATALYSIS; CATALYSTS; DIMERIZATION; DIMERS; PALLADIUM; SILICON; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

ALLYSILANES; ASYMMETRIC SYNTHESIS; PALLADIUM CATALYSTS; SILYLATION;

SILICON COMPOUNDS;

EID: 18744397258     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200401031     Document Type: Article

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