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Volumn 121, Issue 21, 1999, Pages 5095-5096

Synthesis, X-ray structure, and electronic properties of oligosilanes containing pentacoordinate silicon moieties at internal positions

Author keywords

[No Author keywords available]

Indexed keywords

SILANE DERIVATIVE; SILICON;

EID: 0033516291     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982943q     Document Type: Article
Times cited : (62)

References (40)
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    • For reviews, see: (a) Miller, R. D.; Michl, J. Chem. Rev. 1989, 89, 1359. (b) Zeigler, J. M., Fearson, F. W. G., Eds.; Silicon-Based Polymer Science, Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. West, R. J. Organomet. Chem. 1986, 300, 327.
    • (1990) Silicon-Based Polymer Science
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    • For reviews, see: (a) Miller, R. D.; Michl, J. Chem. Rev. 1989, 89, 1359. (b) Zeigler, J. M., Fearson, F. W. G., Eds.; Silicon-Based Polymer Science, Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. West, R. J. Organomet. Chem. 1986, 300, 327.
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    • West, R.1
  • 18
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    • 15 Schubert, U.; Wiener, M.; Köhler, F. H. Chem. Ber. 1979, 112, 708. Quite recently, Tamao and co-workers have reported the synthesis of pseudo- pentacoordinate tetrasilanes having 8-amino-1-naphthyl groups which weakly interact with the internal silicon atoms: Tamao, K.; Asahara, M.; Saeki, T.; Toshimitsu, A. Chem. Lett. 1999, 335.
    • (1979) Chem. Ber. , vol.112 , pp. 708
    • Schubert, U.1    Wiener, M.2    Köhler, F.H.3
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    • 15 Schubert, U.; Wiener, M.; Köhler, F. H. Chem. Ber. 1979, 112, 708. Quite recently, Tamao and co-workers have reported the synthesis of pseudo-pentacoordinate tetrasilanes having 8-amino-1-naphthyl groups which weakly interact with the internal silicon atoms: Tamao, K.; Asahara, M.; Saeki, T.; Toshimitsu, A. Chem. Lett. 1999, 335.
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    • Tamao, K.1    Asahara, M.2    Saeki, T.3    Toshimitsu, A.4
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    • Marciniec, B., Chojnowski, J., Eds.; Gordon and Breach Publishers: Basel, Switzerland
    • (c) Pestunovich, V. A.; Valery, F. S.; Voronkov, M. G. In Progress in Organosilicon Chemistry; Marciniec, B., Chojnowski, J., Eds.; Gordon and Breach Publishers: Basel, Switzerland, 1995; pp 69-82.
    • (1995) Progress in Organosilicon Chemistry , pp. 69-82
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    • All new compounds exhibited satisfactory spectral and analytical data
    • All new compounds exhibited satisfactory spectral and analytical data.
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    • Sheldrick, W.S.1
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    • note
    • eq) bond in 4.
  • 30
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    • Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
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    • Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
    • (1984) Inorg. Chem. , vol.23 , pp. 1378
    • Schomburg, D.1    Krebs, R.2
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    • Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
    • (1954) Acta Crystallogr. , vol.7 , pp. 597
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    • note
    • 3a
  • 39
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    • note
    • Other conformers depicted in Scheme 2 seem to be less stable, due to the steric repulsion between the neighboring rings (conformer B) or an enhanced dipole moment derived from the highly polarized Si-Cl bonds (conformers C and D).


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