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All new compounds exhibited satisfactory spectral and analytical data
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All new compounds exhibited satisfactory spectral and analytical data.
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85069256626
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note
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eq) bond in 4.
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30
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0013325926
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Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
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0000059739
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Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
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Bond lengths in pentacoordinate silicon species are usually longer than in related tetracoordinate species: (a) Deiters, J. A.; Holmes, R. R. J. Am. Chem. Soc. 1990, 112, 7197. (b) Schomburg, D.; Krebs, R. Inorg. Chem. 1984, 23, 1378. Atoji, M.; Lipscomb, W. N. Acta Crystallogr. 1954, 7, 597.
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85069248638
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3a
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34
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0002815665
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The strength of the O-Si coordination bond is reflected in the shift of the v(CO): Macharashvili, A. A.; Shklover, V. E.; Chernikova, N. Yu.; Antipin, M. Yu.; Struchkov, Yu. T.; Baukov, Yu. I.; Oleneva, G. I.; Kramarova, E. P.; Shipov, A. G. J. Organomet. Chem. 1989, 359, 13.
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Kramarova, E.P.8
Shipov, A.G.9
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36
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0004133516
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Gaussian, Inc.: Pittsburgh, PA
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Detailed accounts of the calculated structures and the energies will be reported elsewhere. All calculations were carried out using the program Gaussian 94, Revision E.2: Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb, M. A.; Cheeseman, J. R.; Keith, T.; Petersson, G. A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortiz, J. V.; Foresman, J. B.; Cioslowski, J.; Stefanov, B. B.; Nanayakkara, A.; Challacombe, M.; Peng, C. Y.; Ayala, P. Y.; Chen, W.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Binkley, J. S.; Defrees, D. J.; Baker, J.; Stewart, J. P.; Head-Gordon, M.; Gonzalez, C.; Pople, J. A. Gaussian, Inc.: Pittsburgh, PA, 1995.
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more..
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39
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85069256343
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note
-
Other conformers depicted in Scheme 2 seem to be less stable, due to the steric repulsion between the neighboring rings (conformer B) or an enhanced dipole moment derived from the highly polarized Si-Cl bonds (conformers C and D).
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40
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