DFT studies on the borylation of α,β-unsaturated carbonyl compounds catalyzed by phosphine copper(I) boryl complexes and observations on the interconversions between O- and C-bound enolates of Cu, B, and Si

Organometallics

Volumn 27, Issue 17, 2008, Pages 4443-4454

  Dang, Li ^a   Lin, Zhenyang ^a   Marder, Todd B ^b  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; ARSENIC COMPOUNDS; CARBONYLATION; CHLORINE COMPOUNDS; COPPER ALLOYS; COPPER COMPOUNDS; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSITIONS; ESTERS; ETHYLENE; FORMALDEHYDE; HERBICIDES; ISOMERIZATION; ISOMERS; MECHANISMS; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; PROBABILITY DENSITY FUNCTION; SILICON; THERMODYNAMIC STABILITY; UNSATURATED COMPOUNDS;

ALCOHOLYSIS; ALKOXIDE; BOND METATHESIS; BORYL COMPLEXES; BORYLATION; COPPER(I); DENSITY FUNCTIONAL THEORY CALCULATIONS; DIBORON REAGENT; ENOLATE; ENOLATE INTERMEDIATES; ENOLATES; ESTER GROUPS; INSERTION REACTIONS; INTERCONVERSIONS; KINETIC STABILITY; METHYL ACRYLATES; PROPENAL; REACTION MECHANISMS; UNSATURATED CARBONYL COMPOUNDS;

COPPER;

EID: 52649092372     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om8006294     Document Type: Article

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