Associative versus dissociative mechanisms of phosphate monoester hydrolysis: On the interpretation of activation entropies

ChemPhysChem

Volumn 9, Issue 12, 2008, Pages 1767-1773

  Kamerlin, Shina C L ^a   Florián, Jan ^b   Warshel, Arieh ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^b LOYOLA UNIVERSITY CHICAGO   (United States)

Author keywords

Computational studies; Entropy; Free energy surfaces; Phosphate ester hydrolysis; Reaction mechanisms

Indexed keywords

CHEMICAL ACTIVATION; DEGREES OF FREEDOM (MECHANICS); DISSOCIATION; FREE ENERGY; HYDROLYSIS; SIGNAL TRANSDUCTION;

ANHYDRIDE HYDROLYSIS; CHARGE REDISTRIBUTION; COMPUTATIONAL STUDIES; DISSOCIATIVE MECHANISMS; DISSOCIATIVE PATHWAYS; FREE ENERGY SURFACE; PHOSPHATE ESTER HYDROLYSIS; REACTION MECHANISM;

ENTROPY;

EID: 51249090734     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200800356     Document Type: Article

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