Lithographic mechanical break junctions for single-molecule measurements in vacuum: Possibilities and limitations

New Journal of Physics

Volumn 10, Issue , 2008, Pages

  Martin, Christian A ^a,b   Ding, Dapeng ^a,b   Van Der Zant, Herre S J ^a   Van Ruitenbeek, Jan M ^b  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b LEIDEN UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

BREAK JUNCTIONS; CONDUCTANCE HISTOGRAMS; ELECTRICAL TRANSPORT (CONDUCTIVITY , RESISTIVITY , MOBILITY , ETC.); EXPERIMENTAL CONDITIONS; HEXANEDIAMINE; IN-VACUUM; MECHANICALLY CONTROLLABLE BREAK JUNCTIONS (MCB); MOLECULAR MODELLING; SINGLE MOLECULE MEASUREMENTS; SURFACE DENSITIES;

VACUUM;

EID: 47149093758     PISSN: 13672630     EISSN: None     Source Type: Journal    
DOI: 10.1088/1367-2630/10/6/065008     Document Type: Article

References (52)

1. Reed M A, Zhou C, Muller C J, Burgin T P and Tour J M 1997 Conductance of a molecular junction Science 278 252-4
2. Van Ruitenbeek J M, Alvarez A, Piñeyro I, Grahmann C, Joyez P, Devoret M H, Estéve D and Urbina C 1996 Adjustable nanofabrieated atomic size contacts Rev. Sci. Instrum. 67 108-11
3. Park H, Lim AKL, Alivisatos A P, Park J and McEuen P L 1999 Fabrication of metallic electrodes with nanometer separation by electromigration Appl. Phys. Lett. 75 301-3
4. Li C Z, Sha H and Tao N J 1998 Adsorbate effect on conductance quantization in metallic nanowires Phys. Rev. B 58 6775-8
5. Xu B and Tao N J 2003 Measurement of single-molecule resistance by repeated formation of molecular junctions Science 301 1221-3
6. Haiss W, Van Zalinge H, Higgins S J, Bethell D, Hobenreich H, Schiffrin D J and Nichols R J 2003 Redox state dependence of single molecule conductivity J. Am. Chem. Soc. 125 15294-5
7. Donhauser Z J et al 2001 Conductance switching in single molecules through conformational changes Science 292 2303-7
8. Cui X D, Primak A, Zarate X, Tomfohr J, Sankey O F, Moore A L, Moore T A, Gust D, Harris G and Lindsay S M 2001 Reproducible measurement of single-molecule conductivity Science 294 571-4
9. Vrouwe SAG, Van der Giessen E, Van der Molen S J, Dulic D, Trouwborst M L and Van Wees B J 2005 Mechanics of lithographically defined break junctions Phys. Rev. B 71 035313
10. González M T, Wu S, Huber R, Van der Molen S J, Schönenberger C and Caíame M 2006 Electrical conductance of molecular junctions by a robust statistical analysis Nano Lett. 6 2238-42
11. Lörtscher E, Weber H B and Riel H 2007 Statistical approach to investigating transport through single molecules Phys. Rev. Lett. 98 176807
12. Tsutsui M, Shoji K, Tanigucho M and Kawai T 2008 Formation and self-breaking mechanism of stable atomsized junctions Nano Lett. 8 345-9
13. Huang Z, Chen F, Bennett P A and Tao N 2007 Single molecule junctions formed via Au-thiol contact: Stability and breakdown mechanism J. Am. Chem. Soc. 129 13225-31
14. Park Y S, Whalley A C, Kamenetska M, Steigerwald M L, Hybertsen M S, Nuckolls C and Venkataraman L 2007 Contact chemistry and single-molecule conductance: a comparison of phosphines, methyl sulfides, and amines J. Am. Chem. Soc. 129 15768-9
15. Smit RHM, Noat Y, Untiedt C, Lang N D, Van Hemert M C and Van Ruitenbeek J M 2002 Measurement of the conductance of a hydrogen molecule Nature 419 906-9
16. Kergueris C, Bourgoin J-P, Palatin S, Esteve D, Urbina C, Magoga M and Joachim C 1999 Electron transport through a metal-molecule-metal junction Phys. Rev. B 59 12505-13
17. Reichert J, Ochs R, Beckmann D, Weber H B, Mayor M and Von Löhneysen H 2002 Driving current through single organic molecules Phys. Rev. Lett. 88 176804
18. Fujihira M, Suzuki M, Fujii S and Nishikawa A 2006 Currents through single molecular junction of Au/hexanedithiolate/Au measured by repeated formation of break junction in STM under UHV: effects of conformational change in an alkylene chain from gauche to trans and binding sites of thiolates on gold Phys. Chem. Chem. Phys. 8 3876-84
19. Li Z and Kosov D S 2007 Nature of well-defined conductance of amine anchored molecular junctions Phys. Rev. B 76 035415
20. Tour J M, Jones L II, Pearson D L, Lamba J J S, Burgin T B, Whitesides G M, Aliara D L, Parikh A N and Aire S V 1995 Self-assembled monolayers and multilayers of conjugated thiols a, co-dithiols, and thioacetyl-containing adsorbates. Understanding attachments between potential molecular wires and gold surfaces J. Am. Chem. Soc. 117 9529-34
21. Love J C, Estroff L A, Kriebel J K, Nuzzo R G and Whitesides G M 2005 Self-assembled monolayers of thiolates on metals as a form of nanotechnology Chem. Rev. 105 1103-69
22. Losic D, Shapter J G and Gooding J J 2001 Influence of surface topography on alkanethiol SAMs assembled from solution and by microcontact printing Langmuir 17 3307-16
23. Kawasaki M, Sato T, Tanaka T and Takao K 2000 Rapid self-assembly of alkanethiol monolayers on sputter-grown Au(111) Langmuir 16 1719-28
24. Basch H, Cohen R and Ratner M A 2005 Interface geometry and molecular junction conductance: geometric fluctuation and stochastic switching Nano Lett. 5 1668-75
25. Tomfohr J and Sankey O F 2004 Theoretical analysis of electron transport through organic molecules J. Chem. Phys. 120 1542-54
26. Müller K-H 2006 Effect of the atomic configuration of gold electrodes on the electrical conduction of alkanedithiol molecules Phys. Rev. B 73 045403
27. Haiss W, Nichols R J, Van Zalinge H, Higgins S J, Bethell D and Schiffrin D J 2004 Measurement of single molecule conductivity using the spontaneous formation of molecular wires Phys. Chem. Chem. Phys. 6 4330-7
28. Nishikawa A, Tobita J, Kato Y, Fujii S, Suzuki M and Fujihira M 2007 Accurate determination of multiple sets of single molecular conductance of Au/1,6-hexanedithiol/Au break junctions by ultra-high vacuum-scanning tunneling microscope and analyses of individual current-separation curves Nanotechnology 18 424005
29. Jang S-Y, Reddy P, Majumdar A and Segalman R A 2006 Interpretation of stochastic events in single molecule conductance measurements Nano Lett. 6 2362-7
30. Venkataraman L, Klare J E, Tam I W, Hybertsen M S and Steigerwald M L 2006 Single-molecule circuits with well-defined molecular conductance Nano Lett. 6 458-62
31. Chen F, Li X, Hihath J, Huang Z and Tao N 2006 Effect of anchoring groups on single-molecule conductance : comparative study of thiol-, amine-, and carboxylie-acid-terminated molecules J. Am. Chem. Soc. 128 15874-81
32. Tsutsui M, Teramae Y, Kurokawa S and Sakai A 2006 High-conductance states of single benzenedithiol molecules Appl. Phys. Lett. 89 163111
33. Ulrich J, Esrail D, Pontius W, Venkataraman L, Millar D and Doerrer L H 2006 Variability of conductance in molecular junctions J. Phys. Chem. B 110 2462-6
34. He J, Sankey O, Lee M, Tao N, Li X and Lindsay S 2005 Measuring single molecule conductance with break junctions Faraday Discuss. 131 145-54
35. Xu C, Sun L, Kepley L J and Crooks R M 1993 Molecular interactions between organized, surface-confined monolayers and vapor-phase probe molecules. 6. In-situ FTIR external reflectance spectroscopy of monolayer adsorption and reaction chemistry Anal. Chem. 65 2102-7
36. Brown L O and Hutchison J E 1999 Controlled growth of gold nanoparticles during ligand exchange J. Am. Chem. Soc. 121 882-3
37. Kumar A, Mandai S, Selvakannan P R, Pasricha R, Mandale A B and Sastry M 2003 Investigation into the interaction between surface-bound alkylamines and gold nanoparticles Langmuir 19 6277-82
38. Quek S Y, Venkataraman L, Choi H J, Louie S G, Hybertsen M S and Neaton J B 2007 Amine-gold linked single-molecule junctions: experiment and theory Nano Lett. 7 3477-82
39. Ron H, Matlis S and Rubinstein I 1998 Self-assembled monolayers on oxidised metals. 2. Gold surface oxidative pretrearment, monolayer properties, and depression formation Langmuir 14 1116-21
40. Ron H and Rubinstein 11994 Alkanethiol monolayers on preoxidised gold encapsulation of gold oxide under an organic monolayer Langmuir 10 4566-73
41. [41 ] Agrai't N, Levy Yeyati A and Van Ruitenbeek J M 2003 Quantum properties of atomic-sized conductors Phys. Rep. 377 81-279
42. Krans J M, Muller C J, Yanson IK, Govaert TCM, Hesper R and Van Ruitenbeek J M 1993 One-atom point contacts Phys. Rev. B 48 14721-4
43. Yanson A I, Rubio Bollinger G, Van den Brom H E, Agraït N and Van Ruitenbeek J M 1998 Formation and manipulation of a metallic wire of single gold atoms Nature 395 783-5
44. Rubio G, Agraït N and Vieira S 1996 Atomic-sized metallic contacts: mechanical properties and electronic transport Phys. Rev. Lett. 76 2302-5
45. Li C, Pobelov I, Wandlowski T, Bagrets A, Arnold A and Evers F 2008 Charge transport in single Au/alkanedithiol/Au junctions: coordination geometries and conformational degrees of freedom J. Am. Chem. Soc. 130 318-26
46. Xu B, Xiao X and Tao N J 2003 Measurements of single-molecule electromechanical properties J. Am. Chem. Soc. 125 16164-5
47. Xiao X, Xu B and Tao N J 2004 Measurement of single molecule conductance: benzenedithiol and benzenedimethanethiol Nano Lett. 4 267-71
48. Troisi A and Ratner M A 2006 Molecular signatures in the transport properties of molecular wire junctions: what makes a junction molecular? Small 2 172-81
49. Xue Y and Ratner M A 2003 Microscopic study of electrical transport through individual molecules with metallic contacts. I. Band lineup, voltage drop, and high-field transport Phys. Rev. B 68 115406
50. Stadler R, Thygesen K S and Jakobsen K W 2005 An ab initio study of electron transport through nitrobenzene: the influence of leads and contacts Nanotechnology 16 S155-60
51. Arnold A, Weigend F and Evers F 2007 Quantum chemistry calculations for molecules coupled to reservoirs: formalism, implementation, and application to benzenedithiol J. Chem. Phys. 126 174101
52. Romaner L, Heimel G, Gruber M, Brédas J-L and Zojer E 2006 Stretching and breaking of a molecular junction Small 2 1468-75