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Based on the multimode lead calculation in ref 18. The difference between (100) and (111) electrodes can be large as four orders of magnitude, when based on the one-band ideal leads.
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In our MCBJ setup, we push the two Au electrodes, which are coated with molecules, together to form a contact of conductance greater than GO prior to breaking the junctions so as to produce the STM-like measurements.
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84906398078
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We fit only the curves that do not drop below our detection limit after the contact breaks. This represents about 75% of curves without molecules (20% in MCBJ experiments) and about 95% of curves with molecules in solution (50% in MCBJ experiments).
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84906359880
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We note here that for a quantitative comparison of histograms, it is important to collect data in equimolar solutions of different molecules.
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Although this cutoff is arbitrary, it was chosen to keep ∼15% of the data. Varying this cutoff between 0.25 and 0.5 does not qualitatively affect the histograms.
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0, in agreement with ref 14.
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