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The ring-closing metathesis afforded tie bicyclic compound 8 as the major product (80% yield) and a small amount of monocyclic by-product with ring closing only on one side.
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31
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4544351169
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note
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The synthesis and detailed characterization of the ligand and complexes will be reported separately (manuscript in preparation).
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33
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4544349082
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2 by full-matrix least-squares techniques. Hydrogen atoms were included by using a riding model. There was one molecule of dichloromethane solvent present per formula unit. There was another solvent present and was assigned as dichloroethane. This solvent was disordered and located about an inversion center. CCDC-222192 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+ 44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
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4544221485
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See Supporting Information. The detailed polymerization results for the palladium catalyst will be reported separately.
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