Comparability and reliability of different techniques for the determination of phenolic compounds in virgin olive oil

European Journal of Lipid Science and Technology

Volumn 106, Issue 8, 2004, Pages 540-549

  Hrncirik, Karel ^a   Fritsche, Sonja ^a,b  

^a UNILEVER RESEARCH VLAARDINGEN   (Netherlands)

^b UNILEVER RESEARCH   (United Kingdom)

Author keywords

Analysis; Extraction; Folin Ciocalteu; HPLC; Olive oil; Phenols; Polyphenols; Quantification; SPE

Indexed keywords

OLIVE OIL; PHENOL DERIVATIVE; SOLVENT;

ARTICLE; CHEMICAL ANALYSIS; COLORIMETRY; CORRELATION ANALYSIS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LIQUID LIQUID EXTRACTION; QUANTITATIVE ANALYSIS; RELIABILITY; SOLID PHASE EXTRACTION;

EID: 4544373041     PISSN: 14387697     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejlt.200400942     Document Type: Article

References (36)

1. F. Visioli, C. Galli: Olive oil phenols and their potential effects on human health. J. Agric. Food Chem. 46 (1998) 4292-4296.
2. P. Andrewes, J. L. H. C. Busch, T. de Joode, A. Groenewegen, H. Alexandre: Sensory properties of virgin olive oil polyphenols: Identification of deacetoxy-ligstroside aglycon as a key contributor to pungency. J. Agric. Food Chem. 51 (2003) 1415-1420.
3. M. Tsimidou: Polyphenols and quality of virgin olive oil in retrospect. Ital. J. Food Sci. 10 (1998) 99-116.
4. M. Servili, G. Montedoro: Contribution of phenolic compounds to virgin olive oil quality. Eur. J. Lipid Sci. Technol. 104 (2002) 602-612.
5. E. Psomiadou, X. Konstantinos, K. G. Blekas, M. Z. Tsimidou, D. Boskou: Proposed parameters for monitoring quality of virgin olive oil (Koroneiki cv). Eur. J. Lipid Sci. Technol. 105 (2003) 403-408.
6. M. Brenes, A. Garcia, P. Garcia, J. J. Rios, A. Garrido: Phenolic compounds in Spanish olive oils. J. Agric. Food Chem. 47 (1999) 3535-3540.
7. R. Mateos, J. L. Espartero, M. Trujillo, J. J. Rios, M. Leon-Camacho, F. Alcudia, A. Cert: Determination of phenols, flavones, and lignans in virgin olive oils by solid-phase extraction and high-performance liquid chromatography with diode array ultraviolet detection. J. Agric. Food Chem. 49 (2001) 2185-2192.
8. G. Montedoro, M. Servili, M. Baldioli, R. Selvaggini, E. Miniati, A. Macchioni: Simple and hydrolyzable phenolic-compounds in virgin olive oil. 3. Spectroscopic characterisations of the secoiridoid derivatives. J. Agric. Food Chem. 41 (1993) 2228-2234.
9. F. Angerosa, N. d'Alessandro, F. Corana, G. Mellerio: Characterization of phenolic and secoiridoid aglycones present in virgin olive oil by gas chromatography - chemical-ionization mass spectrometry. J. Chromatogr. 736 (1996) 195-203.
10. R. W. Owen, W. Mier, A. Giacosa, W. E. Hull, B. Spiegelhalder, H. Bartsch: Identification of lignans as major components in the phenolic fraction of olive oil. Clin. Chem. 46 (2000) 976-988.
11. M. Brenes, F. J. Hidalgo, A. Garcia, J. J. Rios, P. Garcia, R. Zamora, A. Garrido: Pinoresinol and 1-acetoxypinoresinol, two new phenolic compounds identified in olive oil. J. Am. Oil Chem. Soc. 77 (2000) 715-720.
12. A. Vazquez-Roncero, C. Janer, M. L. Janer: Phenolic components in olive fruits. III. Polyphenols in olive oil. Grasas Aceites 27 (1976) 185-191.
13. P. Rovellini, N. Cortesi, E. Fedeli: Analysis of flavonoids from Olea Europaea by HPLC-UV and HPLC-elektrospray-MS. Riv. Ital. Sost. Grasse 74 (1997) 273-279.
14. M. Baldioli, M. Servili, G. Perretti, G. Montedoro: Antioxidant activity of tocopherols and phenolic compounds of virgin olive oil. J. Am. Oil Chem. Soc. 73 (1996) 1589-1595.
15. M. Brenes, A. Garcia, P. Garcia, A. Garrido: Rapid and complete extraction of phenols from olive oil and determination by means of a coulometric electrode array system. J. Agric. Food Chem. 48 (2000) 5178-5183.
16. G. Montedoro, M. Servili, M, Baldioli, E. Miniati: Simple and hydrolyzable phenolic-compounds in virgin olive oil. 1. Their extraction, separation, and quantitative and semiquantitative evaluation by HPLC. J. Agric. Food Chem. 40 (1992) 1571-1576.
17. S. Mannino, M. S. Cosio, M. Bertuccioli: High performance liquid chromatography of phenolic compounds in virgin olive oil using amperometric detection. Ital. J. Food Sci. 4 (1993) 363-370.
18. F. Favati, G. Carporale, M. Bertuccioli: Rapid determination of phenol content in extra virgin olive oil. Grasas Aceites 45 (1994) 68-70.
19. F. M. Pirisi, A. Angioni, P. Cabras, V. L. Garau, M. T., S. di Teulada, M. K. dos Santos, G. Bandino: Phenolic compounds in virgin olive oils I. Low-wavelength quantitative determination of complex phenols by high-performance liquid chromatography under isocratic elution. J. Chromatogr. 768 (1997) 207-213.
20. F. M. Pirisi, P. Cabras, C. Falqui Cao, M. Migliorini, M. Muggelli: Phenolic compounds in virgin olive oil. 2. Reappraisal of the extraction, HPLC separation and quantification procedures. J. Agric. Food Chem. 48 (2000) 1191-1196.
21. M. Servili, M. Baldioli, R. Selvaggini, E. Miniati, A. Macchioni, G. Montedoro: High-performance liquid chromatography evaluation of phenols in olive fruit, virgin olive oil, vegetation waters, and pomace and 1D- and 2D-nuclear magnetic resonance characterization. J. Am. Oil Chem. Soc. 76 (1999) 873-882.
22. L. Liberatore, G. Procida, N. d'Alessandro, A. Cichelli: Solid-phase extraction and gas chromatographic analysis of phenolic compounds in virgin olive oil. Food Chem. 73 (2001) 119-124.
23. M. Tsimidou, G. Papadopoulos, D. Boskou: Determination of phenolic-compounds in virgin olive oil by reversed-phase HPLC with emphasis on UV-detection. Food Chem. 44 (1992) 53-60.
24. M. Saitta, C. S. Lo, F. Salvo, G. Di Bella, G. Dugo: Gas chromatographic-tandem mass spectrometric identification of phenolic compounds in Sicilian olive oils. Anal. Chim. Acta 466 (2002) 335.
25. T. Gutfinger: Polyphenols in olive oils. J. Am. Oil Chem. Soc. 58 (1981) 966-968.
26. M. Tasioula-Margari, O. Okogeri: Isolation and characterization of virgin olive oil phenolic compounds by HPLC/UV and GC-MS. J. Food Sci. 66 (2001) 530-538.
27. N. Cortesi, M. Azzolini, P. Rovellini, E. Fedeli: Minor polar components of virgin olive oil. Riv. Ital. Sost. Grasse 72 (1995) 241-251.
28. th Int. Conference 2, 13-16 July, Lisbon (Portugal) 1992, pp. 192-196.
29. F. Favati, G. Carporale, E. Monteleone, M. Bertuccioli: Rapid extraction and determination of phenols in extra virgin olive oil. In: Food flavours: generation, analysis and process influence. Ed. G. Charalamous, Elsevier, Amsterdam (The Netherlands) 1995, pp. 429-438.
30. A. Bendini, M. Bonoli, L. Cerretani, B. Biguzzi, G. Lercker, T. G. Toschi: Liquid-liquid and solid-phase extractions of phenols from virgin olive oil and their separation by chromatographic and electrophoretic methods. J. Chromatogr. 985 (2003) 425-433.
31. V. L. Singleton, J. A. Rossi: Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagents. Am. J. Enol. Viticult. 16 (1965) 144-158.
32. G. Blekas, E. Psomiadou, M. Tsimidou, D. Boskou: On the importance of total phenols to monitor the stability of Greek virgin olive oil. Eur. J. Lipid Sci. Technol. 104 (2002) 340-346.
33. V. L. Singleton, R. Orthofer, R. M. Lamuela-Raventos: Analysis of total phenols and other oxidation substrates and antioxidants by means of Folin-Ciocalteu reagent. Methods Enzymol. 299 (1999) 152-178.
34. L. Mosca, C. de-Marco, F. Visioli, C. Cannella: Enzymic assay for the determination of olive oil polyphenol content; assay conditions and validation of the method. J. Agric. Food Chem. 48 (2000) 297-301.
35. F. Cioni, G. Modi, G. Simiani, S. Tracchi: Evoluzione dei componenti minori polari in oli extravergini di oliva durante la conservazione. Boll. Chim. Igien. 49 (1998) 115-118.
36. M. Esti, L. Cinquante, E. La Notte: Phenolic compounds in different olive varieties. J. Agric. Food Chem. 46 (1998) 32-35.