Click chemistry in materials synthesis. 1. Adhesive polymers from copper-catalyzed azide-alkyne cycloaddition

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 42, Issue 17, 2004, Pages 4392-4403

  Díaz, David D ^a   Punna, Sreenivas ^a   Holzer, Philipp ^a   Mcpherson, Andrew K ^a   Sharpless, K Barry ^a   Fokin, Valery V ^a   Finn, M G ^a  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

Adhesives; Alkynes; Azides; Click chemistry; Copper; Cycloaddition; Transition metal chemistry

Indexed keywords

CLICK CHEMISTRY; CYCLOADDITION; TRANSITIONAL METAL CHEMISTRY;

ADDITION REACTIONS; BRASS; CATALYSIS; CATALYSTS; CHEMICAL BONDS; COPPER; MIXTURES; MONOMERS; PLASTIC ADHESIVES; POLYMERIZATION; STRENGTH OF MATERIALS; SURFACE TREATMENT; SYNTHESIS (CHEMICAL);

ORGANIC POLYMERS;

EID: 4444267581     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.20330     Document Type: Article

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44. 2) and 100 mg of monomer mixtures. The most effective system, supporting at least 25 kg in a peel test for at least 10 hours, was composed of a 1.5:1 mixture of 4 and 14 (azide: alkyne ratio = 1:1).