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Volumn 20, Issue 4, 2004, Pages 1051-1053

"Clicking" Functionality onto Electrode Surfaces

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRODE SURFACES; REDOX POTENTIALS;

EID: 1442357313     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la0362977     Document Type: Article
Times cited : (461)

References (34)
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    • As specific examples, the β carbon of benzoquinone reacts readily with nucleophiles and cyclopentadiene is prone to spontaneous dimerization at room temperature. The Diels-Alder adduct between cyclo-pentadiene and benzoquinone has been observed to slowly revert at room temperature. See: (a) Kemp, D. S.; Vellaccio, F. Organic Chemistry; Worth Publishers Inc.: New York, 1980; pp 758, 1108. (b) Pool, B. E.; White, J. M. Org. Lett. 2000, 22, 3505-3507.
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    • Ferroceneacetylenes were synthesized following previously published literature procedures, (a) Rosenblum, M.; Brawn, N.; Papenmeier, J.; Applebaum, M. J. Organomet. Chem. 1966, 6, 173-180. (b) Barriga, S.; Marcos, C. F.; Riant, O.; Torroba, T. Tetrahedron 2002, 58, 9785-9792.
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    • Ferroceneacetylenes were synthesized following previously published literature procedures, (a) Rosenblum, M.; Brawn, N.; Papenmeier, J.; Applebaum, M. J. Organomet. Chem. 1966, 6, 173-180. (b) Barriga, S.; Marcos, C. F.; Riant, O.; Torroba, T. Tetrahedron 2002, 58, 9785-9792.
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    • note
    • Ad values were -0.3 and -0.4 for 2 and 3, respectively.
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    • note
    • Where γ is equal to the mole fraction of azidoundecanethiol compared to total thiol in the deposition solution.
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    • note
    • An analysis of the electrochemical data reveals that the pseudo-first-order rate constant of product accumulation appears to increase such that the reaction is complete at 3 h even though the degree of completion at 1h predicts that a longer time would be required. This suggests an increase in catalyst activity as the reaction proceeds.


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