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Volumn 6, Issue 11, 2008, Pages 1934-1937

Carbon-rich molecules: Synthesis and isolation of aryl/heteroaryl terminal bis(butadiynes) (HC≡C-C≡C-Ar-C≡C-C≡CH) and their applications in the synthesis of oligo(arylenebutadiynylene) molecular wires

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIVITY; CONJUGATED POLYMERS; OLIGOMERIZATION; ORGANIC COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 43749122371     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b802968g     Document Type: Article
Times cited : (27)

References (42)
  • 32
    • 33750476684 scopus 로고    scopus 로고
    • Ar-C≡C-C≡CH species have generally been used in situ and it has frequently been stated that they are unstable to isolation due to their rapid decomposition or polymerisation: -8544
    • K. West C. Wang A. S. Batsanov M. R. Bryce J. Org. Chem. 2006 71 8541 8544
    • (2006) J. Org. Chem. , vol.71 , pp. 8541
    • West, K.1    Wang, C.2    Batsanov, A.S.3    Bryce, M.R.4
  • 40
    • 12344289263 scopus 로고    scopus 로고
    • Aromatic hydrocarbons are the usual solvents for the removal of a 2-hydroxy-2-propyl group to liberate an alkyne (ref. 18a). The use of polar solvents with higher boiling points (DMF, n-BuOH, DMSO and DMA) have been reported (ref. 18b). We are not aware of THF being used previously. The terminal pyridyl substituents were chosen as they could serve as anchor groups at metal surfaces in future device structures: -4920
    • Z. Novák P. Nemes A. Kotschy Org. Lett. 2004 6 4917 4920
    • (2004) Org. Lett. , vol.6 , pp. 4917
    • Novák, Z.1    Nemes, P.2    Kotschy, A.3
  • 41


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.