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It is worth noting that no cyclopropylidene by-product resulting from addition of an intermediate carbene/carbenoid species to the olefin moiety of the cyclohexene was detected.
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70
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Our initial efforts were unsuccessful in effecting the formation of 4b (ref. [26]).
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Surprisingly, crystallization of compound 20 from a concentrated hexanes solution affords a microcrystalline solid that is stable indefinitely. Crystals of this apparent polymorph are, unfortunately, unsuitable for crystallographic analysis.
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