A synthesis of bicyclo[n.1.0]alkanes having tert-butyl carboxylate or acetamide moiety via the intramolecular 1,3-CH insertion of magnesium carbenoids

Tetrahedron

Volumn 64, Issue 24, 2008, Pages 5711-5720

  Ogata, Shingo ^a   Saitoh, Hideki ^a   Wakasugi, Daisuke ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Bicyclo n.1.0 alkane; C H insertion; Cyclopropane; Magnesium carbenoid; Sulfoxide magnesium exchange

Indexed keywords

ACETAMIDE; ACETAMIDE DERIVATIVE; ALKANE DERIVATIVE; ALKENE DERIVATIVE; BICYCLO COMPOUND; CARBENOID; CARBOXYLIC ACID DERIVATIVE; CYCLOPROPANE; KETONE; MAGNESIUM; SULFOXIDE;

ADDUCTION; ALKYLATION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; CONJUGATION; EPIMERIZATION; ESTERIFICATION; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; OXIDATION; PRIORITY JOURNAL; STEREOCHEMISTRY;

EID: 43149092665     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.04.024     Document Type: Article

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