Generation of magnesium carbenoids from 1-chloroalkyl phenyl sulfoxides with a Grignard reagent and applications to alkylation and olefin synthesis

Tetrahedron

Volumn 60, Issue 25, 2004, Pages 5453-5460

  Satoh, Tsuyoshi ^a   Kondo, Atsushi ^a   Musashi, Jun ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Magnesium carbenoid; Olefin; Sulfone; Sulfoxide; Sulfoxide magnesium exchange

Indexed keywords

1 CHLORO 2 METHYL 2 PHENYLPROPYLPHENYL SULFOXIDE; 1 CHLORO 2,2 DIMETHYL 3 PHENYLPROPYLPHENYL SULFOXIDE; 1 CHLORO 3 (4 METHOXYPHENYL)PROPYLPHENYL SULFOXIDE; ALKENE; BENZENE DERIVATIVE; CARBON; LITHIUM ALPHA SULFONYL CARBANION DERIVATIVE; LITHIUM DERIVATIVE; MAGNESIUM CARBENOID DERIVATIVE; MAGNESIUM DERIVATIVE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; GRIGNARD REACTION; LOW TEMPERATURE; PRIORITY JOURNAL; SYNTHESIS;

EID: 2542609845     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2004.04.063     Document Type: Article

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