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The absorbance (Abs, of the solution and K between metal salt and DPA imine are represented as follows; K, Ccomplex(C mrtalCimine, Abs, εmetalC metal, ε imineCimine, εcomplex CComplex- The replacement of C complex as x gives the equations; K, x/{(Mo, x)(Lo, x, Abs, εmetal(Mo, x, εimine(Lo, x, ε complex x, where Mo is the concentration of the amount of the added metal salts and Lo is the initial concentration of the imine on DPA. Curve fitting of the experimental data gave the coordination constant (K) between metal salt and imine on DPA
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Though 11B is NMR active as well, it is not good in this case since its BF3, complex is insensitive to a change in the environment and therefore not expected to cause a significant change in the chemical shift
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3-: complex is insensitive to a change in the environment and therefore not expected to cause a significant change in the chemical shift.
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58149296675
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2 is 12 equiv.
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2 is 12 equiv.
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-
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