Mechanism of alkyne conversion to carbyne by 14- or 16-electron Os(H)2ClL2X (L = PiPr3; X = OTf or B(C6H3(CF3)2)4)

Journal of Organometallic Chemistry

Volumn 693, Issue 8-9, 2008, Pages 1426-1438

  Lee, Joo Ho ^a   Pink, Maren ^a   Smurnyy, Yegor D ^a   Caulton, Kenneth G ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

Alkyne conversion; Bimetallic Os; Carbyne; Chloride free; Doubly dehalogenated; Exothermic; Monotriflate

Indexed keywords

BIMETALS; DEHALOGENATION; EXOTHERMIC REACTIONS; PHOSPHORUS COMPOUNDS;

ALKYNE CONVERSION; BIMETALLIC OS; CARBYNES; CHLORIDE FREE; DOUBLY DEHALOGENATED; MONOTRIFLATES;

HYDROCARBONS;

EID: 41549132548     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.07.031     Document Type: Article

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