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85163235546
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The formation of complex 18 can be explained by cleavage of the C-Si bond of the methyldiphenyl-substituted vinylidene complex 17b.
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In toluene at 80 °C after 3 h, 8 isomerizes only 25% to 9.
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46
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85163227500
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note
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[14a] Below 130 °C the isomerization of 5a was too slow and above 150 °C the decomposition was too fast.
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47
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[14b] Due to precipitation of decomposition products during the rate measurement of 5b and 5c, only the reaction rate of the isomerization of 5a could be determined.
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