X-ray structure and electrophilic reactivity of a cationic, chiral tungsten(II) methylene complex

Journal of Organometallic Chemistry

Volumn 617, Issue 618, 2001, Pages 520-529

  Jepsen, Aase S ^a   Vogeley, Neil J ^a   White, Peter S ^a   Templeton, Joseph L ^a  

^a The University of North Carolina at Chapel Hill   (United States)

Author keywords

Carbene; Electrophilic; Hydridotris(3,5 dimethylpyrazolyl)borate; Methylene; Thioformaldehyde; Tungsten

Indexed keywords

EID: 0007276610     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(00)00708-7     Document Type: Article

References (69)

1. Fischer E.O., Maasbol A. Angew. Chem. Int. Ed. Engl. 3:1964;580.
2. Dörwald F.Z. Metal Carbenes in Organic Synthesis. 1999;Wiley-VCH, Weinheim.
3. Brookhart M., Liu Y., Goldman E.W., Timmers D.A., Williams G.D. J. Am. Chem. Soc. 113:1991;927.
4. Noels A.F., Demonceau A. J. Phys. Org. Chem. 11:1998;602.
5. Berry D.H., Koloski T.S., Carroll P.J. Organometallics. 9:1990;2952.
6. Doyle M.P., Forbes D.C. Chem. Rev. 98:1998;911.
7. Herndon J.W. Coord. Chem. Rev. 181:1999;177.
8. Grubbs R.H., Chang S. Tetrahedron. 54:1998;4413.
9. Schuster M., Blechert S. Angew. Chem. Int. Ed. Engl. 36:1997;2037.
10. Schrock R.R. Tetrahedron. 55:1999;8141.
11. Schmalz H.G. Angew. Chem. Int. Ed. Engl. 34:1995;1833.
12. Grubbs R.H., Miller S.J., Fu G.C. Acc. Chem. Res. 28:1995;446.
13. Grubbs R.H., Tumas W. Science. 243:1989;907.
14. Pariya C., Jayaprakash K.N., Sarkar A. Coord. Chem. Rev. 168:1998;1.
15. Schrock R.R. Acc. Chem. Res. 23:1990;158.
16. Ivin K.J., Kenwright A.M., Khosravi E., Hamilton J.G. J. Organomet. Chem. 606:2000;37.
17. Anderson R.B. The Fischer-Tropsch Synthesis. 1984;174 Academic Press, New York.
18. Proulx G., Bergman R.G. Science. 259:1993;661.
19. Jolly P.W., Pettit R. J. Am. Chem. Soc. 88:1966;5044.
20. Schrock R.R. J. Am. Chem. Soc. 97:1975;6577.
21. Schwab P., Grubbs R.H., Ziller J.W. J. Am. Chem. Soc. 118:1996;110.
22. Bohle D.S., Clark G.R., Rickard C.E.F., Roper W.R., Wright L.J. J. Organomet. Chem. 358:1988;411.
23. Fryzuk M.D., Johnson S.A., Rettig S.J. Organometallics. 18:1999;4059.
24. Holmes S.J., Schrock R.R. J. Am. Chem. Soc. 103:1981;4599.
25. Werner H., Stüer W., Laubender M., Lehmann C., Herbst-Irmer R. Organometallics. 16:1997;2236.
26. H. Werner, W. Stüer, J. Wolf, M. Laubender, B. Weberndörfer, R. Herbst-Irmer, C. Lehmann, Eur. J. Inorg. Chem. (1999) 1889.
27. Thépot J.Y., Guerchais V., Toupet L., Lapinte C. Organometallics. 12:1993;4843.
28. Patton A.T., Strouse C.E., Knobler C.B., Gladysz J.A. J. Am. Chem. Soc. 105:1983;5804.
29. Heinekey D.M., Radzewich C.E. Organometallics. 17:1998;51.
30. Brookhart M., Tucker J.R., Flood R.C., Jensen J. J. Am. Chem. Soc. 102:1980;1203.
31. Studabaker W.B., Brookhart M. J. Organomet. Chem. 310:1986;C39.
32. Mattson M.N., O'Connor E.J., Helquist P. Org. Synth. 70:1992;177.
33. Kegley S.E., Brookhart M., Husk G.R. Organometallics. 1:1982;760.
34. Mullins S.M., Bergman R.G., Arnold J. Organometallics. 18:1999;4465.
35. J.L. Brumaghim, G.S. Girolami, J. Chem. Soc. Chem. Commun. (1999) 953.
36. Wong W.K., Gladysz J.A., Tam W. J. Am. Chem. Soc. 101:1979;5440.
37. Schwartz J., Gell K.I. J. Organomet. Chem. 184:1980;C1.
38. Tebbe F.N., Parshall G.W., Reddy G.S. J. Am. Chem. Soc. 100:1978;3611.
39. Hill A.F., Roper W.R., Waters J.M., Wright A.H. J. Am. Chem. Soc. 105:1983;5939.
40. A.K. Burrell, G.R. Clark, C.E.F. Rickard, W.R. Roper, A.H. Wright, J. Chem. Soc. Dalton Trans. (1991) 609.
41. Kiel W.A., Lin G.Y., Gladysz J.A. J. Am. Chem. Soc. 102:1980;3299.
42. Kiel W.A., Lin G.Y., Bodner G.S., Gladysz J.A. J. Am. Chem. Soc. 105:1983;4958.
43. Kiel W.A., Lin G.Y., Constable A.G., McCormick F.B., Strouse C.E., Eisenstein O., Gladysz J.A. J. Am. Chem. Soc. 104:1982;4865.
44. Wang Y., Gladysz J.A. Chem. Ber. 128:1995;213.
45. Gunnoe T.B., White P.S., Templeton J.L., Casarrubios L. J. Am. Chem. Soc. 119:1997;3171.
46. Gunnoe T.B., Surgan M., White P.S., Templeton J.L., Casarrubios L. Organometallics. 16:1997;4865.
47. Gunnoe T.B., White P.S., Templeton J.L. Organometallics. 16:1997;3794.
48. Brookhart M., Grant B., Volpe A.F. Jr. Organometallics. 11:1992;3920.
49. W.V. Konze, B.L. Scott, G.J. Kubas, J. Chem. Soc. Chem. Commun. (1999) 1807.
50. Bahr S.R., Boudjouk P. J. Org. Chem. 57:1992;5545.
51. Francisco L.W., White P.S., Templeton J.L. Organometallics. 16:1997;2547.
52. Bastos C.M., Lee K.S., Kjelsberg M.A., Mayr A., Van Engen D., Koch S.A., Franolic J.D., Klooster W.T., Koetzle T.F. Inorg. Chim. Acta. 279:1998;7.
53. van der Shaaf P.A., Abbenhuis R.A.T.M., van der Noort W.P.A., de Graaf R., Grove D.M., Smeets W.J.J., Spek A.L., van Koten G. Organometallics. 13:1994;1433.
54. Shultz A.J., Williams J.M., Schrock R.R., Holmes S.J. Acta Crystallogr., Sect. C. 40:1984;590.
55. Marsella J.A., Folting K., Huffman J.C., Caulton K.G. J. Am. Chem. Soc. 103:1981;5596.
56. Templeton J.L. Adv. Organomet. Chem. 29:1989;1.
57. Churchill M.R., Youngs W.J. Inorg. Chem. 18:1979;2454.
58. Schrock R.R., Glassman T.E., Vale M.G., Kol M. J. Am. Chem. Soc. 115:1993;1760.
59. O'Regan M.B., Liu A.H., Finch W.C., Schrock R.R., Davis W.M. J. Am. Chem. Soc. 112:1990;4331.
60. Pregosin P.S., Macchioni A., Templeton J.L., White P.S., Feng S. Magn. Reson. Chem. 32:1994;415.
61. Frohnapfel D.S., White P.S., Templeton J.L., Rüegger H., Pregosin P.S. Organometallics. 16:1997;3737.
62. Buhro W.E., Etter M.C., Georgiou S., Gladysz J.A., McCormick F.B. Organometallics. 6:1987;1150.
63. H. Werner, M. Steinmetz, K. Peters, H.G. von Schnering, Eur. J. Inorg. Chem. (1998) 1605.
64. Park J.W., Henling L.M., Schaefer W.P., Grubbs R.H. Organometallics. 9:1990;1650.
65. Collins T.J., Roper W.R. J. Organomet. Chem. 159:1978;73.
66. Schuster D.M., White P.S., Templeton J.L. Organometallics. 19:2000;1540.
67. Calderelli J.L., Wagner L.E., White P.S., Templeton J.L. J. Am. Chem. Soc. 116:1994;2878.
68. Schuster D.M., Templeton J.L. Organometallics. 17:1998;2707.
69. Pangborn A.B., Giardello M.A., Grubbs R.H., Rosen R.K., Timmers F.J. Organometallics. 15:1996;1518.