Alkyne ligand enhancement of the substitution lability of mononuclear osmium, ruthenium, and iron carbonyls

Journal of the American Chemical Society

Volumn 120, Issue 7, 1998, Pages 1434-1440

  Pearson, Jean ^a   Cooke, Jason ^a   Takats, Josef ^a   Jordan, R B ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; CARBONYL IRON; HEXAFLUOROBUT 2 YNE; LIGAND; OSMIUM; PHOSPHINE DERIVATIVE; RUTHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 0032564884     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9640049     Document Type: Article

References (69)

1. (a) Schutzenberger, P. Compt. Rend. 1870, 70, 1134.
2. (b) Mond, L.; Langer, C.; Quincke, F. J. Chem. Soc. 1890, 749.
3. Abel, E. J. Organomet. Chem. 1990, 383, 11.
4. Herrmann, W. A. J. Organomet. Chem. 1990, 383, 21.
5. (e) Werner, H. Angew. Chem., Int. Ed. Engl. 1990, 29, 1077.
6. Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds. Comprehensive Organometallic Chemistry; Pergamon: Oxford, 1982; Comprehensive Organometallic Chemistry, Pergamon: Oxford, 1995; Vol. II.
7. Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Eds. Comprehensive Organometallic Chemistry; Pergamon: Oxford, 1982; Comprehensive Organometallic Chemistry, Pergamon: Oxford, 1995; Vol. II.
8. (a) Wender, I.; Pino, P., Eds. Organic Synthesis via Metal Carbonyls; Wiley: New York 1968.
9. (b) Davies, J. A.; Shaver, R. J. The Chemistry of the Metal - Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1985; Vol. 3, Chapter 6.
10. Frontiers in Organic Synthesis; Wender, P. L., Guest Ed. Chem. Rev. 1996, 96 (1).
11. Dombek, R. D. J. Organomet, Chem. 1989, 372, 151.
12. (e) Klinger, R. J.; Rathke, J. W. Progr. Inorg. Chem. 1991, 39, 113.
13. (f) Süss-Fink, G.; Meister, G. Adv. Organomet. Chem. 1993, 35, 41.
14. (g) Guczi, L., Ed. New Trends in CO Activation In Studies in Surface Science and Catalysis; Elsevier: Amsterdam, 1991; Vol. 64.
15. (a) Shvo, Y.; Hazum, E. J. Chem. Soc., Chem. Commun. 1975, 829.
16. (b) Albers, M. O.; Coville, N. J. Coord. Chem. Rev. 1984, 53, 2270.
17. Darensbourg, D. J.; Darensbourg, M. Y.; Walker, N. Inorg. Chem. 1981, 20, 1918.
18. Darensbourg, D. J.; Gray, R. L.; Pala, M. Organometallics 1984, 3, 1928.
19. Bricker, J. C.; Martin, W. P.; Shore, S. G. Organometallics 1987, 6, 2545.
20. (a) Baird, M. C. Chem. Rev. 1988, 88, 1217.
21. (b) Astruc, D. Chem. Rev. 1988, 88, 1189.
22. Bruce, M. I. Coord. Chem. Rev. 1987, 76, 1.
23. Luo, F. H.; Young, S. R.; Li, C. S.; Duan, J. P.; Cheng, C. H. J. Chem. Soc., Dalton Trans. 1991, 2435.
24. (e) Coville, N. J.; Johnston, P.; Lewis, A. E.; Markwell, A. J. J. Organomet. Chem. 1989, 378, 401.
25. (f) Angelici, R. J.; Wang, S. J. Inorg. Chem. 1988, 27, 3233. Noack, K.; Ruch, M. J. Organomet. Chem. 1969, 17, 309.
26. (f) Angelici, R. J.; Wang, S. J. Inorg. Chem. 1988, 27, 3233. Noack, K.; Ruch, M. J. Organomet. Chem. 1969, 17, 309.
27. Lin, Z.; Hall, M. B. Inorg. Chem. 1991, 30, 646 and references therein. Poli, R.; Gordon, J. C. Inorg. Chem. 1991, 30, 4550 and references therein.
28. Lin, Z.; Hall, M. B. Inorg. Chem. 1991, 30, 646 and references therein. Poli, R.; Gordon, J. C. Inorg. Chem. 1991, 30, 4550 and references therein.
29. (a) Lichtenberger, D. L.; Brown, T. L. J. Am. Chem. Soc. 1978, 100, 366.
30. (b) Cohen, M. A.; Brown, T. L. Inorg. Chem. 1976, 15, 1417.
31. Atwood, J. D.; Brown, T. L. J. Am. Chem. Soc. 1976, 98, 3160.
32. (a) Cotton, F. A.;' Darensbourg, D. J.; Kolthammer, B. W. S.; Kudaroski, R. Inorg. Chem. 1982, 21, 1656.
33. (b) Darensbourg, D. J.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1995, 34, 4933.
34. Darensbourg, D. J.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1996, 35, 1529. Darensbourg, D. J.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1996, 35, 1535.
35. Darensbourg, D. J.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1996, 35, 1529. Darensbourg, D. J.; Klausmeyer, K. K.; Reibenspies, J. H. Inorg. Chem. 1996, 35, 1535.
36. (a) Gagné, M. R.; Takats, J. Organometallics 1988, 7, 561.
37. (b) Burn, M. J.; Kiel, G.-Y.; Seils, F.; Takats, J.; Washington, J. J. Am. Chem. Soc. 1989, 111, 6850.
38. Takats, J. J. Cluster Sci. 1992, 3, 479.
39. Mao, T. Ph.D. Thesis, University of Alberta, 1996.
40. Bodner, G. M.; May, M. P.; McKinney, L. E. Inorg. Chem. 1980, 19, 1951.
41. Shen, J.-K.; Gao, Y.-C.; Shi, Q.-Z.; Basolo, F. Inorg. Chem. 1989, 28, 4304.
42. Huber, B. J.; Poë, A. J. Inorg. Chim. Acta 1994, 227, 215.
43. Collmann, J. P.; Roper, W. R. J. Am. Chem. Soc. 1965, 87, 4008. L'Eplattenier, F.; Calderazzo, F. Inorg. Chem. 1968, 7, 1290.
44. Collmann, J. P.; Roper, W. R. J. Am. Chem. Soc. 1965, 87, 4008. L'Eplattenier, F.; Calderazzo, F. Inorg. Chem. 1968, 7, 1290.
45. Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088.
46. Marinelli, G.; Streib, W. E.; Huffman, J. C.; Caulton, K. G.; Gagné, M. R.; Takats, J. Dartiguenave, M.; Chardon, C.; Jackson, S. A.; Eisenstein, O. Polyhedron, 1990, 9, 1867.
47. Caulton, K. G., New J. Chem. 1994, 18, 25.
48. (a) Huang, J.; Hedberg, K.; Pomeroy, R. K. Inorg. Chem. 1990, 29, 3923.
49. (b) Huang, J.; Hedberg, K.; Pomeroy, R. K. Organometallics 1988, 7, 2049.
50. Lüthi, H. P.; Siegbahn, P. E. M.; Almlöf, J. J. Phys. Chem. 1985, 89, 2156.
51. 5 has been determined by: Braga, D.; Greponi, F.; Orpen, A. G. Organometallics 1993, 12, 1481.
52. Li, J.; Schreekenbach, G.; Zeigler, T. J. Am. Chem. Soc. 1995, 117, 486.
53. Ehlers, A. W.; Frenking, G. Organometallics 1995, 14, 423.
54. Poliakoff, M.; Weitz, E. Acc. Chem. Res. 1987, 20, 408. Poliakoff, M.; Turner, J. J. J. Chem. Soc., Dalton Trans. 1974, 2276.
55. Poliakoff, M.; Weitz, E. Acc. Chem. Res. 1987, 20, 408. Poliakoff, M.; Turner, J. J. J. Chem. Soc., Dalton Trans. 1974, 2276.
56. Lewis, K. E.; Golden, D. M.; Smith, G. P. J. Am. Chem. Soc. 1984, 106, 3905.
57. Klobukowski, M.; Decker, S. Details to be published.
58. Espuelas, J.; Esteruelas, M. A.; Lahoz, F. J.; López, A. M.; Oro, L. A.; Valero, C. J. Organomet. Chem. 1994, 468, 223.
59. Ogasawara, M.; MacGregor, S. A.; Streib, W. E.; Folting, K.; Eisenstein, O.; Caulton, K. G. J. Am. Chem. Soc. 1996, 118, 10189.
60. 2-alkyne) compounds, especially in comparison with alkene-type ligands.
61. Glaser, R.; Yoo, Y.-H.; Chen, G. S.; Barnes, C. L. Organometallics 1994, 13, 2578 and references therein. Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791.
62. Glaser, R.; Yoo, Y.-H.; Chen, G. S.; Barnes, C. L. Organometallics 1994, 13, 2578 and references therein. Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791.
63. White, D.; Coville, N. J. Adv. Organomet. Chem. 1994, 36, 95. White, D.; Taverner, B. C.; Coville, N. J.; Wade, P. W. J. Organomet. Chem. 1995, 495, 41.
64. White, D.; Coville, N. J. Adv. Organomet. Chem. 1994, 36, 95. White, D.; Taverner, B. C.; Coville, N. J.; Wade, P. W. J. Organomet. Chem. 1995, 495, 41.
65. Choi, M.-G.; Brown, T. L. Inorg. Chem. 1993, 32, 5603.
66. Choi, M.-G.; Brown, T. L. Inorg. Chem. 1993, 32, 1548 and references therein.
67. Chen, L.; Poë. A. J. Inorg. Chem. 1989, 28, 3641.
68. (a) Rushman, P.; van Buuren, G. N.; Shiralian, M.; Pomeroy, R. K. Organometallics 1983, 2, 693.
69. (b) Washington, J.; McDonald, R.; Takats, J.; Menashe, N.; Reshef, D.; Shvo, Y. Organometallics 1995, 14, 3996.