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Volumn 21, Issue 4, 2002, Pages 707-710

The first planar-chiral stable carbene and its metal complexes

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Indexed keywords

REACTION MIXTURES;

EID: 0000673939     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010679v     Document Type: Article
Times cited : (107)

References (51)
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    • and references therein
    • (a) Louie, J.; Grubbs, R. H. Angew. Chem. 2001, 113, 253; Angew. Chem., Int. Ed. 2001, 40, 247, and references therein.
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    • For recent examples, see: (a) Bolm, C.; Kesselgruber, M.; Hermanns, N.; Hildebrand, J. P.; Raabe, G. Angew. Chem. 2001, 113, 1536; Angew. Chem., Int. Ed. 2001, 40, 1488.
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    • Review on carbenes with ferrocenyl substituents: Bildstein, B. J. Organomet. Chem. 2001, 617-618, 28.
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  • 46
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    • note
    • 2 as reducing agent, ca. 50% conversion was achieved after 24 h at -10 °C. Hydrolysis of the resulting silyl ethers with catalytic amounts of p-TosOH afforded the corresponding alcohols, alas as racemates.
  • 50
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    • Gensin
    • Hall, S. R., du Boulay, D. J., Olthof-Hazekamp, R., Eds.; University of Western Australia
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    • Gentan
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    • Hall, S.R.1


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