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Volumn 112, Issue 4, 2008, Pages 635-642

Does bimolecular charge recombination in highly exergonic electron transfer afford the triplet excited state or the ground state of a photosensitizer?

Author keywords

[No Author keywords available]

Indexed keywords

BENZOQUINONE DERIVATIVES; BIMOLECULAR CHARGE RECOMBINATION; ELECTRON TRANSFER;

EID: 39149117971     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0767718     Document Type: Article
Times cited : (12)

References (91)
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    • Fukuzumi, S.1    Itoh, S.2
  • 38
    • 0001748542 scopus 로고
    • Fox, M. A, Chanon, M, Eds, Elsevier: Amsterdam, Part A, p
    • (a) Wasielewski, M. R. In Photoinduced Electron Transfer; Fox, M. A., Chanon, M., Eds.; Elsevier: Amsterdam, 1988; Part A, p 161.
    • (1988) Photoinduced Electron Transfer , pp. 161
    • Wasielewski, M.R.1
  • 41
    • 0000085682 scopus 로고    scopus 로고
    • Kadish, K. M, Smith, K. M, Guilard, R, Eds, Academic Press: San Diego, CA
    • (a) Gust, D.; Moore, T. A. In The Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, CA, 2000; Vol. 8, pp 153-190.
    • (2000) The Porphyrin Handbook , vol.8 , pp. 153-190
    • Gust, D.1    Moore, T.A.2
  • 46
    • 0000029755 scopus 로고    scopus 로고
    • Harrison, R. J.; Pearce, B.; Beddard, G. S.; Cowan, J. A; Sanders, J. K. M. Chem. Phys. 1987, 116, 429.
    • Harrison, R. J.; Pearce, B.; Beddard, G. S.; Cowan, J. A; Sanders, J. K. M. Chem. Phys. 1987, 116, 429.
  • 54
    • 0000454602 scopus 로고    scopus 로고
    • 3E* value was reported previously, see: (a) Visco, R. E.; Chandross, E. A. Electrochim. Acta 1968, 13, 1187.
    • 3E* value was reported previously, see: (a) Visco, R. E.; Chandross, E. A. Electrochim. Acta 1968, 13, 1187.
  • 68
    • 39149120105 scopus 로고    scopus 로고
    • 1RU* to Q could not be observed by nanosecond laser flash photolysis because the ET rate is faster than the time scale of detection limit.
    • 1RU* to Q could not be observed by nanosecond laser flash photolysis because the ET rate is faster than the time scale of detection limit.
  • 69
    • 39149108306 scopus 로고    scopus 로고
    • ̇+ has been reported. Shida, T. Electronic Absorption Spectra of Radical Ions; Elsevier; New York, 1988.
    • ̇+ has been reported. Shida, T. Electronic Absorption Spectra of Radical Ions; Elsevier; New York, 1988.
  • 73
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    • 42
    • 42
  • 75
    • 39149123987 scopus 로고    scopus 로고
    • The λ value may increase gradually with an increase in the reaction distance (Δr12, We have chosen the two extreme cases (the smallest and the largest ones) in Figure 8. However, the exact dependence of λ on m has yet to be clarified. The X value for BET process depends on the reaction distance
    • 12). We have chosen the two extreme cases (the smallest and the largest ones) in Figure 8. However, the exact dependence of λ on m has yet to be clarified. The X value for BET process depends on the reaction distance.
  • 76
    • 0345996188 scopus 로고    scopus 로고
    • Spin conversion of the RU̇+/Q ion pair is generally faster than the intermolecular BET processes. Thus, the spin conversion process should not be rate determining step; see: (a) Piotrowiak, P. In Photochemistry and Radiation Chemistry: Complementary Methods for the Study of Electron Transfer, Wishart, J. F, Nocera, D. G, Ed, Advances in Chemistry Series, No. 254; American Chemical Society: Washington, DC, 1998; pp 219-230
    • ̇+/Q ion pair is generally faster than the intermolecular BET processes. Thus, the spin conversion process should not be rate determining step; see: (a) Piotrowiak, P. In Photochemistry and Radiation Chemistry: Complementary Methods for the Study of Electron Transfer, Wishart, J. F., Nocera, D. G., Ed.; Advances in Chemistry Series, No. 254; American Chemical Society: Washington, DC, 1998; pp 219-230.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.