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For recent examples, see : a) J. M. Ernsting, C. J. Elsevier, W. G. J. de Lange, K. Timmer, Magn. Res. Chem. 1991, 29, S118; b) B. R. Bender, M. Koller, D. Nanz, W. von Philipsborn, J. Am. Chem. Soc. 1993, 115, 5889; c) T. G. Cherkasova, Yu. S. Varshavsky, I. S. Podkorytov, L. V. Osetrova, Rhodium Express 1993, 0, 21; d) J.-J. Brunet, G. Commenges, D. Neibecker, K. Philippot, L. Rosenberg, Inorg. Chem. 1994, 33, 6373; e) D. J. Law, G. Bigam, R. G. Cavell, Can. J. Chem. 1995, 73, 635; f) C. J. Elsevier, B. Kowall, H. Kragten, Inorg. Chem. 1995, 34, 4836; g) A. Boerner, A. Kless, J. Holz, W. Baumann, A. Tillack, R. Kadyrov, J. Organomet. Chem. 1995, 490, 213; h) A. Boerner, A. Kless, R. Kempe, D. Heller, J. Holz, W. Baumann, Chem. Ber. 1995, 128, 767; i) P. W. Jolly, G. Hopp, E. Passelaigne, W. von Philipsborn, personal communication.
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0343801097
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note
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-3. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-405950. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB21EZ, UK (Fax: Int. code +(1223)336-033; e-mail: deposit@chemcrys.cam.ac.uk).
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64
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0343801096
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in preparation
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A detailed description of the ligand 3o and its coordination chemistry will be given elsewhere: R. B. Bedford, P. A. Chaloner, R. Fornika, P. B. Hitchcock, W. Leitner, in preparation.
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Bedford, R.B.1
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0343801094
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note
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8 metal centre are also important in defining the structure. However, these parameters are identical for all the complexes 1 under scrunity. Although the actual structural basis (ideal P-Rh-P angle, etc.) may be different in other complexes, the relative variations should be comparable, as the same interactions can be expected to operate within the chelate ring.
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72
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unpublished results
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2Rh(hfacac)] is not formed in detectable quantities from 2 according to procedure B even in the presence of an excess of the monodentate ligand; C. Six, W. Leitner, unpublished results.
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Six, C.1
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79
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0342930095
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note
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b) it is interesting to note that molecular mechanics, as described above and in ref. [9], predict a lowest energy conformation of the chelate ring in 3i where one C-H bond is in close proximity to the metal atom and ideally aligned for oxidative addition.
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81
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103Rh nucleus in complexes of type 1 will be given separately. W. Baumann, M. Bühl, E. Dinjus, R. Fornika, M. Kessler, C. Krüger, W. Leitner, C. Six, in preparation.
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0343801090
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2Rh], and a separate treatment seems therefore justified. It should be noted, however, that electronic effects in catalytic reactions that were expected to be mainly sterically controlled have recently attracted much attention [44] and warrant further studies.
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