Concerning the selective protection of (Z)-1,5-syn-ene-diols and (E)-1,5-anfi-ene-diols as allylic triethylsilyl ethers

Organic Letters

Volumn 9, Issue 26, 2007, Pages 5621-5624

  Hicks, Jacqueline D ^a   Huh, Chan Woo ^a   Legg, Ashley D ^a   Roush, William R ^a  

^a Scripps Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHER DERIVATIVE;

ARTICLE; CHEMISTRY;

ETHERS;

EID: 38349165065     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol702588h     Document Type: Article

References (34)

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24. A table of other conditions examined during efforts to optimize the selectivity of silylation of diol 8 is provided in the Supporting Information.
25. The use of imidazole improved the selectivity for allylic alcohol silylation compared to other bases, while DMF and DMAP have little effect on chemoselectivity. See Supporting Information for details.
26. 1H NMR spectroscopy.
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