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8
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0035681095
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Prepared as reported for the synthesis of ent-6: Andersen, O. P.; Barrett, A. G. M.; Edmunds, J. M.; Hachiya, S.-I.; Hendrix, J. A.J Horita, K.; Malecha, J. W.; Parkinson, C. J.; VanSickle, A. Can. J. Chem. 2001, 79, 1562.
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Prepared as reported for the synthesis of ent-6: Andersen, O. P.; Barrett, A. G. M.; Edmunds, J. M.; Hachiya, S.-I.; Hendrix, J. A.J Horita, K.; Malecha, J. W.; Parkinson, C. J.; VanSickle, A. Can. J. Chem. 2001, 79, 1562.
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9
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37049072545
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14
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33847017688
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The absolute stereochemistry of C(17)-OH of 10 was assigned by Mosher ester analysis of an analogue of 13; see Supporting Information for details.
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The absolute stereochemistry of C(17)-OH of 10 was assigned by Mosher ester analysis of an analogue of 13; see Supporting Information for details.
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-
-
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15
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-
33847023911
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1H NMR analysis of the corresponding Mosher esters; see Supporting Information for details.
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1H NMR analysis of the corresponding Mosher esters; see Supporting Information for details.
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17
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0000063664
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These conditions have previously been employed for the cyclization of allylic trichloroacetimidates: Bongini, A, Cardillo, G, Orena, M, Sandri, S, Tomasini, C. J. Org. Chem. 1986, 51, 4905
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These conditions have previously been employed for the cyclization of allylic trichloroacetimidates: Bongini, A.; Cardillo, G.; Orena, M.; Sandri, S.; Tomasini, C. J. Org. Chem. 1986, 51, 4905.
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18
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0001434093
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