Analytical techniques for medicinal and aromatic plants

Stewart Postharvest Review

Volumn 3, Issue 4, 2007, Pages

  Krüger, Hans ^a   Schulz, Hartwig ^a  

^a INSTITUTE FOR EPIDEMIOLOGY AND PATHOGEN DIAGNOSTICS   (Germany)

Author keywords

Distillation; Extraction; Headspace; Microtechniques; Sample preparation; Vibrational spectroscopy

Indexed keywords

EID: 36348998785     PISSN: None     EISSN: 17459656     Source Type: Journal    
DOI: 10.2212/spr.2007.4.4     Document Type: Review

References (95)

1. Wichtl M , Brinckmann JA and Lindenmaier MP (eds). Herbal drugs and phytopharmaceuticals, 3rd ed. Medpharm Scientific Publishers, CRC Press Boca Raton FL; 2004.
2. Teuscher E. Gewürzdrogen, Wissenschaftliche Verlagsgesellschaft mbH Stuttgart; 2003.
3. Hänsel R, Sticher O and Steinegger E. Pharmakognosie - Phytopharmazie, 6. Aufl., Springer Verlag, Berlin; 1999.
4. Bhat SV, Nagasampagi BA and Sivakumar M. Chemistry of natural products, 1st ed. Springer Verlag, Berlin; 2005.
5. Sherma J and Fried B (eds). Chromatographic Science Series, Vol. 55. Handbook of thin-layer chromatography. Marcel Dekker, New York; 1991.
6. Hübschmann HJ. Handbuch der GC/MS, VCH Verlagsgesellschaft mbH, Weinheim; 1996.
7. Günzler H and Williams A (eds). Handbook of analytical techniques, Wiley-VCH, Verlag GmbH, Weinheim; 2001.
8. Böttcher H, Günther I and Bomme U. Quantitative changes in ingredients of valerian-roots (Valeriana officinalis L.) during the postharvest period. Journal of Medicinal and Spice Plants 2006: 11: 149-153.
9. Cantwell MJ and Reid MS. Postharvest physiology and handling of fresh culinary herbs. Journal of Herbs, Spices and Medicinal Plants 1993: 1: 83-127.
10. Böttcher H, Günther I and Franke R. Quantitative changes of the essential ingredients of sage (Salvia officinalis L.) during the postharvest period. Journal of Medicinal and Spice Plants 2002: 7: 382-386.
11. Veselinov B, Martinov M, Adamovic D and Mueller J. Influence of mechanical processing on quality of peppermint (Mentha x piperita L.). Journal of Medicinal and Spice Plants 2004: 7: 382-386.
12. Bux M, Graf J, Heindl A and Müller J. Detection of spatial and temporal moisture and temperature distribution by contactless surface temperature measurement during drying of red clover (Trifolium pratense L.) and artichoke (Cynara scolymus) on a belt-dryer. Journal of Medicinal and Spice Plants 2006: 11: 186-190.
13. Müller J. Trocknung von Arzneipflanzen mit Solarenergie [Dissertation]. Stuttgart: Universität Hohenheim; 1992.
14. Landwehr D and Pahl MH. Kaltzerkleinerung von Gewürzen. Internationale Zeitschrift für Lebensmittel-Technologie und -Verfahrenstechnik 1986: 37: 174-185.
15. Krüger H, Schulz H, Steuer B and Zeiger B. Analytische Schnellmethoden zur Evaluierung ätherischer Öle in Genbankmaterial. Fachtagung "Arznei- und Gewürzpflanzen", Tagungsband: 75-80, Gießen; 1998.
16. Lopez R, Aznar M, Cacho J and Ferreira V. Determination of minor and trace volatile compounds in wine by solid-phase extraction and gas chromatography with spectrometric detection. Journal of Chromatography A 2002: 966: 167-177.
17. Krüger H. Separation of essential oil components from distillation water. Euro Cosmetics 2004: 11/12: 20-22.
18. Halkier BA and Gershenzon J. Biology and biochemistry of glucosinolates. Annual Review of Plant Biology 2006: 57 : 303-333.
19. Boelens M, de Valois P and Wobben HJ. Volatile flavour compounds from onion. Journal of Agricultural and Food Chemistry 1971: 19: 984-991.
20. 2: effect of pressure and temperature on capsaicinoid and colour extraction efficiency. Food Chemistry 2004: 87: 51-58.
21. Perakis C, Louli V and Magoulas K. Supercritical fluid extraction of black pepper oil. Journal of Food Engineering 2005: 71: 386-393.
22. Ibanez E, Cifuentes A, Crego AL, Senorans FJ, Cavero S and Reglero G. Combined use of supercritical fluid extraction, micellar electrokinetic chromatography, and reverse phase high performance liquid chromatography for the analysis of antioxidants from rosemary (Rosmarinus officinalis L.). Journal of Agricultural and Food Chemistry 2000: 48: 4060- 4065.
23. Richter BE, Jones BA, Ezzel JL, Porter NL, Avdalovic N and Pohl C. Accelerated solvent extraction: a technique for sample preparation. Analytical Chemistry 1996: 6: 1033-1039.
24. Höfler F. Beschleunigte Lösungsmittelextraktion (ASE). DIONEX Anwendungsbeispiele. 2000 p. 65.
25. Höfler F. Beschleunigte Lösungsmittelextraktion (ASE). DIONEX Anwendungsbeispiele. 2000 p. 81.
26. Höfler F. Beschleunigte Lösungsmittelextraktion (ASE). DIONEX Anwendungsbeispiele. 2000 p. 83.
27. Höfler F. Beschleunigte Lösungsmittelextraktion (ASE). DIONEX Anwendungsbeispiele. 2000 p. 111.
28. Ferhat MA, Tigrine-Kordjani N, Chemat S, Meklati BY and Chemat F. Rapid extraction of volatile compounds using a new simultaneous microwave distillation: solvent extraction device. Chromatographia 2007: 65: 217-222.
29. Kustrak D, Martinis Z, Kuftinec J and Blazevic N. Composition of the essential oils of some Thymus and Thymbra species. Flavour and Fragrance Journal 1990: 5: 227-231.
30. PharmEur Europäisches Arzneibuch 5. Ausgabe, Grundwerk; 2005.
31. Nickerson GB and Likens ST. Gas chromatographic evidence for the occurrence of hop oil components in beer. Journal of Chromatography 1966: 21: 1-5.
32. Widaja R, Craske JD and Wooton M. Changes in volatile components of paddy, brown and white fragrant rice during storage. Journal of the Science of Food and Agriculture 1996: 71: 218-224.
33. Stahl E. Eine neue Apparatur zur gravimetrischen Erfassung kleinster Mengen ätherischer Öle. Mikrochemie 1953: 40: 367-372.
34. Godefroot M, Sandra P and Verzele M. New method for quantitative essential oil analysis. Journal of Chromatography 1981: 203: 325-335.
35. th International Symposium on Essential Oils, Berlin, 1993.
36. Briechle R, Dammertz W and Guth H. Bestimmung ätherischer Öle in Drogen. GIT Laborzeitschrift 1997: 7: 749-753.
37. Krüger H. Wasserdampfdestillation in Festphasenkartuschen. Pharmazie in unserer Zeit: 1995: 24: 96-97.
38. Buchholz KD and Pawliszyn J. Determination of phenols by solid-phase microextraction and gas-chromatographic analysis. Environmental Science and Technology. 1993: 27: 2844-2848.
39. Belliardo F, Bicchi C, Cordero C, Liberto E, Rubiolo P and Sgorbini B. Head space- Solid Microextraction in the Analysis of the Volatile Fraction of Aromatic and Medicinal Plants. Journal of Chromatographic Science 2006: 44: 416-429.
40. Jirovetz L, Buchbauer G, Shafi MP and Kaniampady MM. Chemotaxonomical analysis of the essential oil aroma compounds of four different Ocimum species from southern India. European Food Research and Technology 2003: 217: 120-124.
41. Bicchi C, Cordero C, IORI C, Rubiolo P and Sandra P. Headspace sorptive extraction (HSSE) in the headspace analysis of aromatic and medicinal plants. Journal of High Resolution Chromatography 2000: 23: 539-546.
42. Tholl D, Boland W, Hansel A, Loreto F, Röse USR and Schnitzler JP. Practical approaches to plant volatile analysis. The Plant Journal 2006: 45: 540-560.
43. Dettmer K and Engewald W. Adsorbent materials commonly used in air analysis for adsorptive enrichment and thermal desorption of volatile organic compounds. Analytical and Bioanalytical Chemistry 2002: 373: 490-500.
44. Boland W, Ney P, Jaenicke L and Gassmann G. A "closed-loop- stripping" technique as a versatile tool for metabolic studies of volatiles. In: Analysis of volatiles, Schreier P (ed.). Walter de Gruyter, Berlin; 1984: pp. 371-373.
45. Wagner H, Bladt S and Zgainski EM. Drogenanalyse. Spinger, Berlin, Heidelberg, New York; 1983.
46. Frey HP and Zieloff K. Qualitative und quantitative Dü nnschichtchromatographie, VCH, Weinheim, New York, Basel, Cambridge; 1992.
47. Reich E and Blatter A. Applications of HPTLC for qualitative and quantitative analysis of medicinal plants. Journal of Medicinal and Spice Plants. 2002: 7: 416-421.
48. Gocan S and Cimpan G. Review of the analysis of medicinal plants by TLC: modern approaches. Journal of Liquid Chromatography & Related Technologies 2004: 27: 1377-1411.
49. Sandra P and Bicchi C (eds). Capillary gas chromatography in essential oil analysis. Huethig, Heidelberg, Basel, New York; 1987.
50. Schreier P. Chromatographic studies of biogenesis of plant volatiles. Huethig, Heidelberg, Basel, New York; 1984.
51. König WA and Hochmuth DH. Enantioselective gas chromatography in flavor and fragrance analysis: Strategies for the identification of known and unknown plant volatiles. Journal of Chromatographic Science 2004: 42: 423-439.
52. Bicchi C, Brunelli C, Cravotto G, Rubiolo P, Galli M and Mendicuti F. Cyclodextrin derivatives in enantiomer GC separation of volatiles. Part XXI: Complexation of some terpenoids with 2-O-acetyl-3-O-methyl- and 2-O-methyl-3-O-acetyl-6-O-t- hexyldimethylsilyl-gamma-cyclodextrins: Molecular mechanics and molecular dynamics. Journal of Separation Science 2003: 26: 1479-1490.
53. Mosandl A. Authenticity assessment: A permanent challenge in food flavor and essential oil analysis. Journal of chromatographic science 2004: 42: 440-449.
54. Cimpan G and Gocan S. Analysis of medicinal plants by HPLC: recent approaches. Journal of Liquid Chromatography & Related Technologies 2002: 25: 2225-2292.
55. Schulz H. Analysis of coffee, tea, cocoa, tobacco, spices, medicinal and aromatic plants, and related products. In: Near-infrared spectroscopy in agriculture, Roberts C, Workman J, Reeves J (eds), American Society of Agronomy - Crop Science of America, Madison, USA, Agronomy Monograph 2004: 44: 345-376.
56. Baranska M and Schulz H. Application of infrared and Raman spectroscopy for analysis of selected medicinal and spice plants: a review. Journal of Medicinal and Spice Plants 2006: 11: 72-80.
57. Schuz H and Baranska M. Identification and quantification of valuable plant substances by IR and Raman spectroscopy. Vibrational Spectroscopy 2007: 43: 13-25.
58. Toxopeus H and Bouwmeester HJ. Improvement of caraway essential oil and carvone production in The Netherlands. Industrial Crops and Products. 1993: 1 : 295-301.
59. Schulz H, Drews HH, Quilitzsch R and Krüger H. Application of near infrared spectroscopy for the quantification of quality parameters in selected vegetables and essential oil plants. Journal of Near Infrared Spectroscopy 1998: 6: A125-A130.
60. Fehrmann A, Schulz H and Pank F. Non-destructive NIRS-measurements in caraway (Carum carvi L.) and fennel (Foeniculum vulgare Mill.) fruits. International Symposium "Breeding Research on Medicinal and Aromatic Plants", Quedlinburg, Germany; 1995: 418-421.
61. Schulz H, Drews HH and Krüger H. Rapid NIRS determination of quality parameters in leaves and isolated essential oils of mentha species. Journal of Essential Oil Research 1999: 11: 185.
62. Schulz H and Baranska M. Application of vibrational spectroscopy methods in essential oil analysis. Perfumer & Flavorist 2005: 30: 28-44.
63. Junghanns W and Krüger H. Vergleich von 9 verschiedenen Majoransorten bzw. - herkünften auf Ertragsverhalten, Blattanteil, Morphologie und Inhaltsstoffe. Herba Germanica 1995: 3: 78-81.
64. Lawrence BM. Progress in essential oils. Perfumer and Flavorist 1984; 9: 49.
65. Sarer E, Scheffer JJC and Baerheim Svendsen A. Composition of the essential oil of Origanum majorana grown in different localities in Turkey. Planta Medica 1985: 209-212.
66. Schulz H, Krüger H, Steuer B, and Pank F. Bestimmung von Inhaltsstoffen des Majorans (Origanum majorana L.) mittels Nah-Infrarot-Spektroskopie. Zeitschrift für Arznei- und Gewürzpflanzen 1999: 4: 62-67.
67. Schulz H, Steuer B, Krüger H, Schütze W, Junghanns W and Weinreich B. Schnelle Erfassung von Qualitätsparametern in Rosmarinblättern (Rosmarinus officinalis L.) mittels Nah- Infrarotspektroskopie. Zeitschrift für Arznei- und Gewürzpflanzen 2001: 6: 79-84.
68. Axcell B, Tulej R and Murray JP. An ultra-fast system for hop analysis. I. The determination of alpha-acids and moisture by near infrared reflectance spectroscopy. Brewers Digest. 1981: 56: 18-19.
69. Axcell B, Tulej R and Murray JP. An ultra-fast system for hop analysis. II. The determination of beta-acids and prediction of hop storage index by near infrared reflectance spectroscopy. Brewers Digest 1981: 56: 32-33.
70. Schulz HB, Pfeffer S and KrügerH. Potential of near infrared spectroscopy for supporting breeding and cultivation of medicinal and spice plants. NIR News 2002: 13: 10.
71. Schulz H, Schrader B, Quilitzsch R, Pfeffer S and Krüger H. Rapid classification of basil chemotypes by various vibrational spectroscopy methods. Journal of Agricultural and Food Chemistry 2003: 51: 2475-2481.
72. Schulz H, Baranska M, Quilitzsch R and Schütze W. Determination of alkaloids in capsules, milk and ethanolic extracts of poppy (Papaver somniferum L.) by ATR-FT-IR and FT- Raman spectroscopy. Analyst 2004: 129: 917-920.
73. Schulz H, Baranska M, Belz HH, Rösch P, Strehle MA and Popp J. Chemotaxonomic characterisation of essential oil plants by vibrational spectroscopy measurements. Vibrational Spectroscopy 2004: 35: 81-86.
74. Baranska M, Schulz H, Rösch P, Strehle MA and Popp J. Identification of secondary metabolites in medicinal and spice plants by NIR-FT-Raman microspectroscopic mapping. Analyst 2004: 129: 926-930.
75. Baranska M, Schulz H, Siuda R, Strehle MA, Rösch P, Popp J, Joubert E and Manley M. Quality of Harpagophytum procumbens and its related pharmaceutical products by means of NIR-FT-Raman spectroscopy. Biopolymers 2005: 77: 1-8.
76. Schulz H, Baranska M, Quilitzsch R, Schütze W and Lösing G. Characterization of peppercorn, pepper oil, and pepper oleoresin by vibrational spectroscopy methods. Journal of Agricultural and Food Chemistry 2005: 53: 3358-3363.
77. Baranski R, Baranska M, Schulz H, Simon PW and Nothnagel T. Single seed Raman measurements allow taxonomical discrimination of Apiaceae accessions collected in gene banks. Biopolymers 2006: 81: 497-505.
78. Baranska M, Schulz H, Joubert E and Manley M. In situ flavanoid analysis by FT-Raman spectroscopy: Identification, distribution and quantification of aspalathin in green rooibos (Aspalathus linearis). Analytical Chemistry 2006: 78: 7716-7721.
79. Baranska M, Schulz H and Christensen. Structural changes of polyactylenes in American ginseng root can be observed in situ by using Raman spectroscopy. Journal of Agricultural and Food Chemistry 2006: 54: 3629-3635.
80. Schulz H, Drews HH, Quilitzsch R and Krüger H. Application of near infrared spectroscopy for the quantification of quality parameters in selected vegetables and essential oil plants. Journal of Near Infrared Spectroscopy 1998: 6: A125-A130.
81. th International Conference on NIRS, Verona (Italy). Davies AMC and Giangiacomo R (eds). NIR Publications, Chichester (UK); 2000: pp. 499-501.
82. th International Conference on NIRS, Kyongju (Südkorea); 2002.
83. Schulz H, Krüger H, Steuer B and Pank F. Bestimmung von Inhaltsstoffen des Majorans (Origanum majorana L.) mittels Nah-Infrarot-Spektroskopie. Zeitschrift für Arznei- und Gewürzpflanzen. 1999: 4: 62-67.
84. Pfeffer S, Krüger H, Schütze W and Schulz H. Schnelle Erfassung von Qualitätsparametern in Kamillenblüten mit Hilfe der Nah-Infrarotspektroskopie. Drogenreport 2002: 15: 29-32.
85. Schulz H, Steuer B and Krüger H. Schnelle und zerstörungsfreie Bestimmung sekundärer Inhaltsstoffe in Teedrogen, Gewürzen und ätherischen Ölen mittels Nah-Infrarot- Spektroskopie (NIRS). In: Proceedings XXXIV. Vortragstagung der DGQ, Freising- Weihenstephan (Germany); 22-23 March 1999: pp. 43-54.
86. Schulz H, Quilitzsch R, Drews HH and Krüger H. Estimation of minor components in caraway, fennel and carrots by NIRS - comparison of results from dispersive and Fourier- Transform instruments. International Agrophysics. 2000: 14: 249-253.
87. th International Conference on NIRS, Verona (Italy). Davies AMC and Giangiacomo R (eds). NIR Publications, Chichester (UK); 2000: pp. 447-453.
88. Schulz H, Steuer B and Schütze W. Rotbusch-Tee. Deutsche Apotheker Zeitung 2000: 140: 3809-3815.
89. Joubert E and Schulz H. Production and quality aspects of rooibos tea and related products. A review. Journal of Applied Botany and Food Quality 2006: 80: 138-144.
90. Liu GL, Cho RK and Hong JH. Application of near infrared spectroscopy for non-destructive evaluation of ginsenoside content. Near Infrared Analysis 2000: 1: 45-48.
91. Liu GL, Sohn MR, Cho RK and Hong JH. Discrimination of geographical origin and cultivation years of ginseng by near infrared reflectance spectroscopy. Near Infrared Analysis 2000: 1: 41-44.
92. Pudelko-Körner C, Fischer A, Lentzen H and Glombitza KW. Quantitative Fourier Transform near-infrared reflectance spectroscopy of sennosides in Senna pods. Pharmaceutical and Pharmacological Letters 1996: 1 : 34-36.
93. Schulz H and Albroscheit G. High-performance liquid chromatographic characterization of some medical plant extracts used in cosmetic formulas. Journal of Chromatography 1988: 442: 353-36.
94. Schulz H, Pfeffer S, Quilitzsch R, Steuer B and Reif K. Rapid and non-destructive determination of the echinacosoid content in Echinacea roots by ATR-IR and NIR spectroscopy. Planta Medica 2002: 68: 926-929.
95. Iwamoto M, Cho RK, Uozumi J and Iino K. Near infrared reflectance spectrum of red pepper and its applicability to determination of capsaicin content. Nippon Shokuhin Kogyo Gakkaishi 1984: 31 : 120-125.