Relationships between hydration number, water activity and density of aqueous sugar solutions

Food Chemistry

Volumn 106, Issue 4 SPEC. ISS., 2008, Pages 1443-1453

  Gharsallaoui, Adem ^a   Rogé, Barbara ^a   Génotelle, Jean ^b   Mathlouthi, Mohamed ^a  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

^b Groupement Technique de Sucreries   (France)

Author keywords

Density; Disaccharide; Hydration number; Monosaccharide; Water activity coefficient

Indexed keywords

SUGAR; WATER;

ARTICLE; HYDRATION; SPECTROSCOPY; TEMPERATURE; THERMODYNAMICS;

EID: 35448958512     PISSN: 03088146     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.foodchem.2007.02.047     Document Type: Article

References (33)

1. Abderafi S., and Bounahmidi T. Measurement and modeling of atmospheric pressure vapour-liquid equilibrium data for binary, ternary and quaternary mixtures of sucrose, glucose, fructose and water components. Fluid phase Equilibria 93 (1994) 337-351
2. Akhumov E.I. Hydration of sucrose in solution. Zhurnal Prikladnoi Khimii 48 (1975) 458-460
3. Akhumov E.I. Hydration of sucrose in solutions. Zhurnal Fizicheskoi Khimii 55 (1981) 1496-1499
4. Allen A.T., and Wood R.M. Molecular association in the sucrose-water system. Sugar Technology Reviews 2 (1974) 165-180
5. Bressan C., and Mathlouthi M. Thermodynamic activity of water and sucrose and the stability of crystalline sugar. Zuckerindustrie 119 (1994) 652-658
6. Bubnik Z., Kadlec P., Urban D., and Bruhns M. Sugar technologists manual. Chemical and physical data for sugar manufacturers and users. 8th ed. (1995), Bartens, Berlin pp. 167-170
7. Catté M., Dussap C.-G., Achard C., and Gros J.-B. Excess properties and solid-liquid equilibria for aqueous solutions of sugar using a UNIQUAC model. Fluid Phase Equilibria 96 (1994) 33-50
8. Cooke S.A., Jónsdóttir S.O., and Westh P. The vapour pressure of water as a function of solute concentration above aqueous solutions of fructose, sucrose, raffinose, erythritol, xylitol, and sorbitol. Journal of Chemical Thermodynamics 34 (2002) 1545-1555
9. Crowe J.H., Crowe L.M., Oliver A.E., Tsvetkova N., Wolkers W., and Tablin F. The trehalose myth revisited: Introduction to a symposium on stabilization of cells in the dry state. Cryobiology 43 (2001) 89-105
10. Elias M.E., and Elias A.M. Trehalose + water fragile system: Properties and glass transition. Journal of Molecular Liquids 83 (1999) 303-310
11. Emmerich A. Density data for sucrose solutions. Zuckerindustrie 119 (1994) 120-123
12. Ferreira O., Brignole E.A., and Macedo E.A. Phase equilibria in sugar solutions using the A-UNIFAC model. Industrial and Engineering Chemistry Research 42 (2003) 6212-6222
13. Galema S.A., and Høiland H. Stereochemical aspects of hydration of carbohydrates in aqueous solutions. 3. Density and ultrasound measurements. Journal of Physical Chemistry 95 (1991) 5321-5326
14. Guinier A. La structure de la matière (1980), Hachette, Paris pp. 131-132
15. Handbook of chemistry and physics (69th ed.), 1988-1989.
16. Hough L., and Khan R. Intensification of sweetness. Trends in Biochemical Sciences 3 (1978) 61-63
17. ICUMSA (1994). Specifications and Tables SPS-4, Densimetry and tables official, SPS-4 (pp. 1-11).
18. Immel S., and Lichtenthaler F.W. The conformation of sucrose in water: A molecular dynamics approach. Liebigs Annalen 7 (1995) 1925-1937
19. Larsen B.L., Rasmussen P., and Fredenslund A. A modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing. Industrial & Engineering Chemistry Research 26 (1987) 2274-2286
20. Lerbret A., Bordat P., Affouard F., Descamps M., and Migliardo F. How homogeneous are the trehalose, maltose, and sucrose water solutions? An insight from molecular dynamics simulations. Journal of Physical Chemistry B 109 (2005) 11046-11057
21. Mathlouthi M. X-Ray diffraction study of the molecular association in aqueous solutions of d-fructose, d-glucose, and sucrose. Carbohydrate Research 91 (1981) 113-123
22. Mathlouthi M., and Génotelle J. In: Mathlouthi M., and Reiser P. (Eds). Sucrose (1994), Blackie Academic and Professional 127-154
23. Mathlouthi M., Luu C., Meffroy-Biget A.M., and Luu D.V. Laser-Raman study of solute-solvent interactions in aqueous solutions of d-fructose, d-glucose, and Sucrose. Carbohydrate Research 81 (1980) 213-223
24. Rüegg M., and Blanc B. The water activity of honey and related sugar solutions. Lebensmittel-Wissenschaft und-Technologie 14 (1981) 1-6
25. Scatchard G. The hydration of sucrose in water solution as calculated from vapor-pressure measurements. Journal of American Chemical Society 43 (1921) 2406-2418
26. Schönert H. Zur Hydratation von nichtelektrolyten in wässrigen Lössungen. Zeitschrift Fur Physikalische Chemie Neue Folge 61 (1968) 262-270
27. Starzak M., and Mathlouthi M. Water activity in concentrated sucrose solutions and its consequences for the availability of water in the film of syrup surrounding sugar crystal. Zuckerindustrie 127 (2002) 175-185
28. Starzak M., and Mathlouthi M. Temperature dependence of water activity in aqueous solutions of sucrose. Food Chemistry 96 (2006) 346-370
29. Starzak M., Peacock S.D., and Mathlouthi M. Hydration number and water activity models for the sucrose-water system: A critical review. Critical Reviews in Food Science and Nutrition 40 (2000) 327-367
30. Stokes R.H., and Robinson R.A. Interactions in aqueous nonelectrolyte solutions. I. Solute-solvent equilibria. Journal of Physical Chemistry 70 (1966) 2126-2131
31. Taylor J.B., and Rawlinson J.S. Thermodynamic properties of aqueous solutions of glucose. Transactions of the Faraday Society 51 (1955) 1183-1192
32. Van Hook A. The thermodynamic activity of concentrated sugar solutions. Zuckerindustrie 112 (1987) 597-600
33. Wang W. Instability, stabilization, and formulation of liquid protein pharmaceuticals. International Journal of Pharmaceutics 185 (1999) 129-188